Description: Das Projekt "Diffusion and advection with sorption of anions, cations and non-polar molecules in organo-clays at varying thermo-chemical conditions - validation by analytical methods and molecular simulation" wird vom Umweltbundesamt gefördert und von Leibniz Universität Hannover, Institut für Bodenkunde durchgeführt. The sorption of anions in geotechnical multibarrier systems of planned high level waste repositories (HLWR) and of non-ionic and organic pollutants in conventional waste disposals are in the center of recent research. In aquatic systems, persistent radionuclides such as 79Se, 99Tc, 129I exist in a form of anions. There is strongly increasing need to find materials with high sorption capacities for such pollutants. Specific requirements on barrier materials are long-term stability of adsorbent under various conditions such as T > 100 C, varying hydrostatic pressure, and the presence of competing ions. Organo-clays are capable to sorb high amounts of cations, anions and non-polar molecules simultaneously having selectivity for certain ions. This project is proposed to improve the understanding of sorption and desorption processes in organo-clays. Additionally, the modification of material properties under varying chemical and thermal conditions will be determined by performing diffusion and advection experiments. Changes by sorption and diffusion will be analyzed by determining surface charge and contact angles. Molecular simulations on models of organo-clays will be conducted in an accord with experiments with aim to understand and analyze experimental results. The computational part of the project will profit from the collaboration of German partner with the group in Vienna, which has a long standing experience in a modeling of clay minerals.
Types:
SupportProgram
Origin: /Bund/UBA/UFORDAT
Tags: Hannover ? Eberesche ? Organo-Ton ? Wien ? Material ? Adsorptionsmittel ? Resistenz ? Anionen ? Bodenkunde ? Kationen ? Radionuklid ? Lehm ? Abfalllager ? Gebühr ? Desorption ? Tonmineral ? Abfall ? Analyseverfahren ? Bestimmungsmethode ? Chemikalien ? Ionen ? Modellversuch ? Organischer Schadstoff ? Simulation ? Sorption ? Angelfischerei ? Modellierung ? Beseitigung ? Ökonomischer Gewinn ? Advektion ? Bedarf ? Diffusion ? Forschung ? Mineral ? Persistenz ? Schadstoff ? Änderung ? HINDERNIS ? RATIFIKATION ? VERHAELTNIS ? EXPERIMENT ? Vermehrung ? SPEZIFISCH ? DRUCK ? FAEHIG ? GEPLANT ? STARK ? STOFFEIGENSCHAFTEN ? ERFORDERNIS ? Selektivität ? TEIL ? ERGEBNIS ? Thermochemischer Vorgang ? BETRAG ? GRUPPE ? Gebühr [Abgabe] ? UNTER ? DAUER ? KONVENTIONELL ? LEISTUNGSFAEHIGKEIT ? VERARBEITEN ? NEU ? OBERFLAECHE ? PROJEKT ?
Region: Lower Saxony
Bounding box: 9.16667° .. 9.16667° x 52.83333° .. 52.83333°
License: cc-by-nc-nd/4.0
Language: Deutsch
Time ranges: 2012-01-01 - 2024-11-29
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