Chromium (Cr) is introduced into the environment by several anthropogenic activities. A striking ex-ample is the area around Kanpur in the Indian state of Uttar Pradesh, where large amounts of Cr-containing wastes have been recently illegally deposited. Hexavalent Cr, a highly toxic and mobile contaminant, is present in significant amounts in these wastes, severely affecting the quality of sur-roundings soils, sediments, and ground waters. The first major goal of this study is to clarify the solid phase speciation of Cr in these wastes and to examine its leaching behavior. X-ray diffraction and synchrotron-based X-ray absorption spectroscopy techniques will be employed for quantitative solid phase speciation of Cr. Its leaching behavior will be studied in column experiments performed at un-saturated moisture conditions with flow interruptions simulating monsoon rain events. Combined with geochemical modeling, the results will allow the evaluation of the leaching potential and release kinetics of Cr from the waste materials. The second major goal is to investigate the spatial distribution, speciation, and solubility of Cr in the rooting zone of chromate-contaminated soils surrounding the landfills, and to study the suitability of biochar as novel soil amendment for mitigating the deleterious effects of chromate pollution. Detailed field samplings and laboratory soil incubation studies will be carried out with two agricultural soils and biochar from the Kanpur region.
Im letzten Jahrzehnt war der grönländische Eisschild mehreren Extremereignissen ausgesetzt, mit teils unerwartet starken Auswirkungen auf die Oberflächenmassebilanz und den Eisfluss, insbesondere in den Jahren 2010, 2012 und 2015. Einige dieser Schmelzereignisse prägten sich eher lokal aus (wie in 2015), während andere fast die gesamte Eisfläche bedeckten (wie in 2010).Mit fortschreitendem Klimawandel ist zu erwarten, dass extreme Schmelzereignisse häufiger auftreten und sich verstärken bzw. länger anhalten. Bisherige Projektionen des Eisverlustes von Grönland basieren jedoch typischerweise auf Szenarien, die nur allmähliche Veränderungen des Klimas berücksichtigen, z.B. in den Representative Concentration Pathways (RCPs), wie sie im letzten IPCC-Bericht genutzt wurden. In aktuellen Projektionen werden extreme Schmelzereignisse im Allgemeinen unterschätzt - und welche Konsequenzen dies für den zukünftigen Meeresspiegelanstieg hat, bleibt eine offene Forschungsfrage.Ziel des vorgeschlagenen Projektes ist es, die Auswirkungen extremer Schmelzereignisse auf die zukünftige Entwicklung des grönländischen Eisschildes zu untersuchen. Dabei werden die unmittelbaren und dauerhaften Auswirkungen auf die Oberflächenmassenbilanz und die Eisdynamik bestimmt und somit die Beiträge zum Meeresspiegelanstieg quantifiziert. In dem Forschungsprojekt planen wir zudem, kritische Schwellenwerte in der Häufigkeit, Intensität sowie Dauer von Extremereignissen zu identifizieren, die - sobald sie einmal überschritten sind - eine großräumige Änderung in der Eisdynamik auslösen könnten.Zu diesem Zweck werden wir die dynamische Reaktion des grönländischen Eisschilds in einer Reihe von Klimaszenarien untersuchen, in denen extreme Schmelzereignisse mit unterschiedlicher Wahrscheinlichkeit zu bestimmten Zeitpunkten auftreten, und die Dauer und Stärke prognostisch variiert werden. Um indirekte Effekte durch verstärktes submarines Schmelzen hierbei berücksichtigen zu können, werden wir das etablierte Parallel Ice Sheet Model (PISM) mit dem Linearen Plume-Modell (LPM) koppeln. Das LPM berechnet das turbulente submarine Schmelzen aufgrund von Veränderungen der Meerestemperatur und des subglazialen Ausflusses. Es ist numerisch sehr effizient, so dass das gekoppelte PISM-LPM Modell Ensemble-Läufe mit hoher Auflösung ermöglicht. Folglich kann eine breite Palette von Modellparametern und Klimaszenarien in Zukunftsprojektionen in Betracht gezogen werden.Mit dem interaktiv gekoppelten Modell PISM-LPM werden wir den Beitrag Grönlands zum Meeresspiegelanstieg im 21. Jahrhundert bestimmen, unter Berücksichtigung regionaler Veränderungen von Niederschlag, Oberflächen- und Meerestemperaturen, und insbesondere der Auswirkungen von Extremereignissen. Ein Hauptergebnis wird eine Risikokarte sein, die aufzeigt, in welchen kritischen Regionen Grönlands zukünftige extreme Schmelzereignisse den stärksten Eisverlust zur Folge hätten.
To overcome the limitation in spatial and temporal resolution of methane oceanic measurements, sensors are needed that can autonomously detect CH4-concentrations over longer periods of time. The proposed project is aimed at:- Designing molecular receptors for methane recognition (cryptophane-A and -111) and synthesizing new compounds allowing their introduction in polymeric structure (Task 1; LC, France); - Adapting, calibrating and validating the 2 available optical technologies, one of which serves as the reference sensor, for the in-situ detection and measurements of CH4 in the marine environments (Task 2 and 3; GET, LAAS-OSE, IOW) Boulart et al. (2008) showed that a polymeric filmchanges its bulk refractive index when methane docks on to cryptophane-A supra-molecules that are mixed in to the polymeric film. It is the occurrence of methane in solution, which changes either the refractive index measured with high resolution Surface Plasmon Resonance (SPR; Chinowsky et al., 2003; Boulart et al, 2012b) or the transmitted power measured with differential fiber-optic refractometer (Boulart et al., 2012a; Aouba et al., 2012).- Using the developed sensors for the study of the CH4 cycle in relevant oceanic environment (the GODESS station in the Baltic Sea, Task 4 and 5; IOW, GET); GODESS registers a number of parameters with high temporal and vertical resolution by conducting up to 200 vertical profiles over 3 months deployment with a profiling platform hosting the sensor suite. - Quantifying methane fluxes to the atmosphere (Task 6); clearly, the current project, which aims at developing in-situ aqueous gas sensors, provides the technological tool to achieve the implementation of ocean observatories for CH4. The aim is to bring the fiber-optic methane sensor on the TRL (Technology Readiness Level) from their current Level 3 (Analytical and laboratory studies to validate analytical predictions) - to the Levels 5 and 6 (Component and/or basic sub-system technology validation in relevant sensing environments) and compare it to the SPR methane sensor, taken as the reference sensor (current TRL 5). This would lead to potential patent applications before further tests and commercialization. This will be achieved by the ensemble competences and contributions from the proposed consortium in this project.
We are currently facing the urgent need to improve our understanding of carbon cycling in subsoils, because the organic carbon pool below 30 cm depth is considerably larger than that in the topsoil and a substantial part of the subsoil C pool appears to be much less recalcitrant than expected over the last decades. Therefore, small changes in environmental conditions could change not only carbon cycling in topsoils, but also in subsoils. While organic matter stabilization mechanisms and factors controlling its turnover are well understood in topsoils, the underlying mechanisms are not valid in subsoils due to depth dependent differences regarding (1) amounts and composition of C-pools and C-inputs, (2) aeration, moisture and temperature regimes, (3) relevance of specific soil organic carbon (SOC) stabilisation mechanisms and (4) spatial heterogeneity of physico-chemical and biological parameters. Due to very low C concentrations and high spatio-temporal variability of properties and processes, the investigation of subsoil phenomena and processes poses major methodological, instrumental and analytical challenges. This project will face these challenges with a transdisciplinary team of soil scientists applying innovative approaches and considering the magnitude, chemical and isotopic composition and 14C-content of all relevant C-flux components and C-fractions. Taking also the spatial and temporal variability into account, will allow us to understand the four-dimensional changes of C-cycling in this environment. The nine closely interlinked subprojects coordinated by the central project will combine field C-flux measurements with detailed analyses of subsoil properties and in-situ experiments at a central field site on a sandy soil near Hannover. The field measurements are supplemented by laboratory studies for the determination of factors controlling C stabilization and C turnover. Ultimately, the results generated by the subprojects and the data synthesized in the coordinating project will greatly enhance our knowledge and conceptual understanding of the processes and controlling factors of subsoil carbon turnover as a prerequisite for numerical modelling of C-dynamics in subsoils.
Calcium supply in tropical soils is variable and frequently low. In spite of the heterogeneous Ca supply, some plant species, such as figs, maintain high Ca concentrations in their tissues. Figs are keystone species with more than proportional importance for the functioning of a tropical rain forest. High Ca concentrations in fig fruits may render them particularly attractive for frugivorous vertebrates. We propose to study the whole Ca cycling from soil through a selected fig species, Ficus insipida Willd. and frugivorous bats, their main dispersers, back to soil. The study will be conducted in Panama on sites differing in soil Ca status to assess the importance of soil Ca availability for fig fruit content and bat reproduction. We will quantify aboveground Ca fluxes for 16 trees along a gradient of Ca availability in soil. We will determine (1) Ca concentrations in soils, figs and leaves, (2) nutritional quality of fig and other bat-dispersed fruits and their importance for Ca balance in relation to reproduction of fruit-eating bats, (3) Ca fluxes with litterfall, throughfall, stemflow, bat pellets and faeces, (4) the importance of the contribution of bats to the Ca cycle of individual fig trees, and (5) the effect of fig trees on soil Ca concentrations.
Populations of P. fortinii from allover Europe are examined using microsatellites to construct gene genealogies and infer evolutionary history. The tree-root endophyte Phialocephala fortinii s.l. (mitosporic Ascomycota) is the dominant colonizer of conifer root systems in forests in the northern hemisphere. P. fortinii s.l. is genetically highly diverse and forms a complex of several cryptic species. Recombination occurs or has occurred within cryptic species and to some extent also among them (introgression). Cryptic species occur sympatrically and they can form large thalli, but it remains unclear whether the observed patterns of spatial distribution reflect local climax situations or are the results of recent gene and genotype flow. One of the key objectives will be to estimate population genetic parameters (eg. migration rates, genotype flow, recombination) within and among populations of cryptic species in forests where man-mediated genotype flow can be excluded. Other key objectives are the determination of the number, frequency, distribution and evolutionary history of the cryptic species in Europe and to identify the driving forces for speciation. The approach will be multidisciplinary and will include standard mycological and microbiological methods as well as molecular genetic techniques such as microsatellite fingerprinting and DNA sequencing. The evolutionary history of haplotypes at both the population and species level will be reconstructed and the results will be compared with known patterns of pleistocenic glaciations and postglacial recolonization of host trees. The project will be a significant contribution to the understanding of the population and evolutionary genetics of a versatile and ecologically extremely successful fungal genus and it will shed light on the effects of pleistocenic and postglacial climatic changes on fungal speciation.
Introduction: In Malaysia, excessive nutrients from livestock waste management systems are currently released to the environment. Particularly, large amounts of manure from intensive pig production areas are being excreted daily and are not being fully utilised. Alternatively, the excess manure can be applied as an organic fertiliser source in neighbouring cropping systems on the small landholdings of the pig farms to improve soil fertility so that its nutrients will be available for crop uptake instead of being discharged into water streams. Thus, there is a need for better tools to analyse the present situation, to evaluate and monitor alternative livestock production systems and manure management scenarios, and to support farmers in the proper management of manure and fertiliser application. Such tools are essential to quantify, and assess nutrient fluxes, manure quality and content, manure storage and application rate to the land as well as its environmental effects. Several computer models of animal waste management systems to assist producers and authorities are now available. However, it is felt that more development is needed to adopt such models to the humid tropics and conditions of Malaysia and other developing countries in the region. Objectives: The aim is to develop a novel model to evaluate nutrient emission scenarios and the impact of livestock waste at the landscape or regional level in humid tropics. The study will link and improve existing models to evaluate emission of N to the atmosphere, and leaching of nutrients to groundwater and surface water. The simulation outputs of the models will be integrated with a GIS spatial analysis to model the distribution of nutrient emission, leaching and appropriate manure application on neighbouring crop lands and as an information and decision support tool for the relevant users.
Aktuelle wissenschaftliche Studien legen nahe, dass die aktuelle Erderwärmung durch Treibhausgasemissionen hervorgerufen wird, die vom Menschen verursacht sind. Um gegen diese Entwicklung geeignete Maßnahmen ergreifen zu können bzw. um zu überprüfen, ob solche Maßnahmen von Erfolg gekrönt sind, ist es notwendig, die Schadstoffkonzentrationen inklusive der zugehörigen Emissionsquellen genau zu kennen. Diese Informationen sind bisher jedoch sehr lückenhaft und beruhen auf sogenannten 'bottom-up' Berechnungen. Da diese Kalkulationen nicht auf direkten Messungen beruhen, weisen sie große Ungenauigkeiten auf und sind außerdem nicht in der Lage, bisher unbekannte Emissionsquellen zu identifizieren. In dem hier vorgestellten Projekt soll ein mesoskaliges Netzwerk für die Überwachung von Luftschadstoffen wie CO2, CH4, CO, NO2 und O3 aufgebaut werden, das auf dem neuartigen Konzept der differentiellen Säulenmessung beruht. Bei diesem Ansatz wird die Differenz zwischen den Luftsäulen luv- und leewärts einer Stadt gebildet. Diese Differenz ist proportional zu den emittierten Schadstoffen und somit eine Maßzahl für die Emissionen, welche in der Stadt generiert werden.Mithilfe dieser Methode wird es in Zukunft möglich sein, städtische Emissionen über lange Zeiträume hinweg zu überwachen. Damit können neue Informationen über die Generierung und Umverteilung von Luftschadstoffen gewonnen werden. Wir werden u.a. folgende zentrale Fragen beantworten: Wie verhält sich der tatsächliche Trend der CO2, CH4 und NO2 Emissionen in München über mehrere Jahre? Wo sind die Emissions-Hotspots? Wie akkurat sind die bisherigen 'bottom-up' Abschätzungen? Wie effektiv sind die Maßnahmen zur Emissionsreduzierung tatsächlich? Sind vor allem für Methan weitere Maßnahmen zur Reduzierung der Emissionen notwendig? Zu diesem Zweck werden wir ein vollautomatisiertes Messnetzwerk aufbauen und passende Methoden zur Modellierung entwickeln, welche u.a. auf STILT (Stochastic Time-Inverted Lagrangian Transport) und CFD (Computational Fluid Dynamics) basieren. Mithilfe der Modellierungsresultate werden wir eine Strategie entwerfen, wie städtische Netzwerke zur Überwachung von Luftschadstoffen aufgebaut werden müssen, um repräsentative Ergebnisse zu erhalten. Außerdem können mit den so gewonnenen städtischen Emissionszahlen z.B. dem Stadtreferat, den Stadtwerken München oder der Bayerischen Staatsregierung Möglichkeiten zur Beurteilung der Effektivität der angewandten Klimaschutzmaßnahmen an die Hand gegeben werden. Das hier vorgestellte Messnetzwerk dient somit als Prototyp, um die grundlegenden Fragen zum Aufbau eines solchen Sensornetzwerks zu klären, damit objektive Aussagen zu städtischen Emissionen möglich werden. Dieses Projekt ist weltweit einmalig und wird zukunftsweisende Ergebnisse liefern.
Existing models of soil organic matter (SOM) formation consider plant material as the main source of SOM. Recent results from nuclear magnetic resonance analyses of SOM and from own incubation studies, however, show that microbial residues also contribute to a large extent to SOM formation. Scanning electron microscopy showed that the soil mineral sur-faces are covered by numerous small patchy fragments (100 - 500 nm) deriving from microbial cell wall residues. We will study the formation and fate of these patchy fragments as continuously produced interfaces in artificial soil systems (quartz, montmorillonite, iron oxides, bacteria and carbon sources). We will quantify the relative contributions of different types of soil organisms to patchy fragment formation and elucidate the effect of redox con-ditions and iron mineralogy on the formation and turnover of patchy fragments. The develop-ment of patchy fragments during pedogenesis will be followed by studying soil samples from a chronosequence in the forefield of the retreating Damma glacier. We will characterize chemical and physical properties of the patchy fragments by nanothermal analysis and microscale condensation experiments in an environmental scanning electron microscope. The results will help understanding the processes at and characteristics of biogeochemical interfaces.
The decomposition of terrestrial organic material such as leaf litter represents a fundamental ecosystem function in streams that delivers energy for local and downstream food webs. Although agriculture dominates most regions in Europe and fungicides are applied widely, effects of currently used fungicides on the aquatic decomposer community and consequently the leaf decomposition rate are largely unknown. Also potential compensation of such hypothesised adverse effects due to nutrients or higher average water temperatures associated with climate change are not considered. Moreover, climate change is predicted to alter the community of aquatic decomposers and an open question is, whether this alteration impacts the leaf decomposition rate. The current projects follows a tripartite design to answer these research questions. Firstly, a field study in a vine growing region where fungicides are applied in large amounts will be conducted to whether there is a dose-response relationship between the exposure to fungicides and the leaf decomposition rate. Secondly, experiments in artificial streams with field communities will be carried out to assess potential compensatory mechanisms of nutrients and temperature for effects of fungicides. Thirdly, field experiments with communities exhibiting a gradient of taxa sensitive to climate change will be used to investigate potential climate-related effects on the leaf decomposition rate.
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