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Intercalibration of the intra-laboratory 40Ar/39Ar reference material Drachenfels sanidine

The dataset contains full 40Ar/39Ar geochronological data completed by multi-collector noble-gas mass spectrometry using the laser total fusion technique on sanidine separated from the Drachenfels trachyte (Drachenfels, Bad Godesberg, Germany). The Drachenfels sanidine represents a useful intra-laboratory reference material for laser work. The purpose of the dataset is to share updated intercalibration data for the intra-laboratory Drachenfels sanidine, relative to the widespread fluence monitors Alder Creek sanidine and Fish Canyon sanidine, that can be used in future 40Ar/39Ar geochronological studies. W. McIntosh (New Mexico Geochronology Research Laboratory, Socorro, NM), P. Renne (Berkeley Geochronology Center, Berkeley, CA) and J.R. Wijbrans (Vrije Universiteit Amsterdam, NL) kindly provided splits of FCs, ACs and DRA1, respectively. The Ar laserprobe facility was realized with the financial support of CNR. The CO2 laser system was acquired within the PNRR – Mission 4, “Education and Research” - Component 2, “From research to business” - Investment line 3.1, “Fund for the creation of an integrated system of research and innovation infrastructures” - Project IR0000025 MEET.

Geochemical and modal proportion analysis of phase assemblages on experimental samples investigating the fluid-absent melting of metasediments

The melting relations, phase compositions, and trace element partitioning behavior during metasediment partial melting were investigated by high pressure and temperature experiments (300 and 900 MPa, 750–950 °C). The here published dataset includes all geochemical analysis of experimental products and starting materials, Raman identification of experimental minerals, and quantification of experimental phase proportions. From this dataset, we provided new insights into the origin of rare-metal enriched granites.

New geochemical analyses on samples drilled on the mid-Norwegian margin during IODP Expedition 396, ODP Leg 104 and DSDP Leg 38

New major and trace element data on samples collected during the IODP (International Ocean Discovery Program) Expedition 396, ODP (Ocean Drilling Program) Leg 104, and DSDP (Deep Sea Drilling Project) Leg 38 on the Vøring margin, including 209 whole rocks analyses on hard rock samples (basalt, granite, andesite, dacite and rhyolite), 13 whole rock data on ash layers, and 381 in situ pXRF analyses on basaltic rocks.

Hydrogeological characterisation of a Lower Jurassic rock unit at the Mont Terri - I: Data of the Opalinus Clay and the Staffelegg Formation

Opalinus Clay is chosen as host rock for the deep geological disposal of nuclear waste in Switzerland and is also being considered in Germany. The underlying Staffelegg Formation comprises potentially water-bearing layers. To investigate the hydrogeological setting of these two formations at the Swiss Rock Laboratory in Mont Terri two bore holes have been drilled in the framework of the HS-Experiment (Hydrogeological Survey). The 58 m long BHS-1 starts in the Lower Shaly facies of the Opalinus Clay, crossects the entire Staffelegg formation and ends in the Triassic Klettgau formation. The shorter BHS-2 provides additional data from the carbonate-rich sandy facies and Lower Shaly facies of the Opalinus Clay. The presented data publication provides geochemical, mineralogical and petrophysical parameters of rocks, pore water and (dissolved) gases from these two drillings. In the following the main measured parameter are listed: geochemical composition of bulk rock and single minerals, isotopic data of carbonates and S isotopes of bulk rock, cation exchange, analyses of organic compounds, bulk rock and clay mineralogy, bulk density, porosity, water content, noble gases, pore water composition, composition and isotopes of dissolved gases and water isotopes.

Mo and O isotope data for Tonga-Kermadec arc lavas and DSDP site 204 sediments

Other

Expert dataset: A whole rock geochemical dataset for magmatic rocks drilled on the mid-Norwegian margin

Other

Combined noble gas analyses and p-T estimates from mineral separates and xenoliths, as well as noble gas analyses from free gas: A study of the origin of young(est) volcanism and magmatic activity in western Bohemia, Czech Republic

The western Eger Rift in the Czech Republic is a currently inactive volcanic area characterized by earthquake swarms and degassing of mantle-derived fluids. Gases obtained from minerals and from repeatedly sampled free gases are used to trace the origin and evolution of volatiles and determine the conditions of the magma reservoir. Helium isotopes in fluids and minerals are up to 5.95 RA, with 20Ne/22Ne ratios up to ~11.0 and 21Ne/22Ne ratios up to ~0.048, suggesting a mixed atmospheric-mantle source for neon. Some crustal input may also be present. The slightly lower-than-mantle He isotopic ratios and the variability in Ne isotopic compositions indicate that these gases may have been impacted by a subduction-related crustal component during the Variscan (or Hercynian) Orogeny. 40Ar/36Ar ratios are higher than atmospheric levels and arrive up to 4680, indicating a mixture of atmospheric and mantle sources. Thermobarometry of pyroxene mineral grains reveals temperatures and pressures suggesting that the crystallization started at ~75 km depth and ended at ~20 km depth following a smooth p-T course. This implies diverse magma ascent conditions. A total of 56 gas samples were collected from two intensively degassing areas in the western Eger Rift (Czech Republic), namely the mofette fields of Bublák and Hartoušov. From the Hartoušov mofette field, 24 gas samples of fluids ascending in two boreholes (F1:∼28 m depth and F2: ∼108 m depth) and 22 samples of gases emerging in two nearby ponds [surface expressions Hartoušov Mofette (HM) and Hartoušov Mofette South (HMS)] were taken. Ten samples were collected from a pond in the Bublák mofette field (Bbl). In addition to the gas samples, ten rock samples were collected from rock exposures [i.e. Libá (LI) and Číhaná (CI) in quarries, Horní Slavkov (HS1&2), Pila (PI), Dolní Dražov (DD), Kadaň (KN), Horní Paseky (HP), and Slapany (SL) in natural cliffs, and Hlinky (HL) in an outcrop] within the western Eger rift area. In addition, six samples of ultramafic nodules/xenoliths were obtained from the Quaternary tephra deposit of the Mýtina maar and from Železná hůrka scoria cone. Gas and rock sampling:

Cathodoluminescence zoning images of Lower El Cajete quartz and sanidine crystals, Valles Caldera, New Mexico, USA

The Valles Caldera, New Mexico, USA was created by two caldera-forming eruptions at ~1.6 and ~1.1 Myr. Since then, post-caldera activity has consisted of lava domes, lava flows, large explosive phases, and a hydrothermal system active today. Possibly the youngest eruption sequence, El Cajete, was emplaced 74.4 ± 1.3 ka (Zimmerer et al., 2016) and began with pyroclastic surges, followed by pyroclastic density currents (PDCs) and pumice-rich Plinian pyroclastic fall (Self et al., 1988). The objective of this project was to characterize crystal grains from the early El Cajete sequence, in terms of morphology and textures, using scanning electron microscopy (SEM). The early El Cajete differs from the later part of the sequence in its greater stratigraphic and lithologic complexity, having been formed from not only pyroclastic fall (like the later El Cajete) but also surge beds and PDCs. This dataset was collected under the national open access action at Istituto Nazionale di Geofisica e Vulcanologia, Sezione di Pisa SEM/EDS facility supported by WP3 ILGE – MEET project, PNRR – EU Next Generation Europe program, MUR grant number D53C22001400005. This allowed me to obtain the present dataset of 31 cathodoluminescence (CL) images of 30 quartz crystals and one sanidine crystal.

Geochemical and isotopic compositions of minerals and bulk rocks of the Chachimbiro Volcanic Complex (Northern Andes, Ecuador)

This dataset provides geochemical data from from the Quaternary Chachimbiro Volcanic Complex (CVC), situated in the Western Cordillera of Ecuador, Northern Andes (0.468°N, 78.287°W). The CVC is subdivided into 4 eruptive stages (CH1, CH2, CH3, CH4) ranging in age between ~400 and ~4 ka ago (Bellver-Baca et al., 2020). The CH1 stage consists of andesitic flows erupted between 405.7 ± 20.0 and 298.6 ± 32.9 ka with collapse of the pre-existing cone at the end of the effusive period (File #1). The following CH2 stage (121.75 ± 23.2 -36.08 ± 2.8 ka) consists of andesitic to dacitic domes and pyroclastic rocks which also suffered a collapse event as shown by the scar and the uprooted domes in the hillside of the edifice (File #1). The CH3 unit (36.08 ± 0.28 – 22.73 ± 0.12 ka) consists of two main andesitic to dacitic domes (Hugá and Albují: H and A, respectively, in File #1) and effusive rocks. CH4 consists of a volumetrically small rhyodacitic pyroclastic unit which was produced by a lateral blast dated at 5.5-5.8 ky ago. A younger pyroclastic episode (<4.15 ka ago) has been related to the Pucará dome (Comida, 2012), but rocks of this event have not been investigated in the present study. The bulk rock and mineral data are used to reconstruct the plumbing system beneath the CVC during its ~400 ka long lifetime. Since the temporal geochemical evolution of CVC bulk rocks towards higher values of adakite-like indices (e.g., Sr/Y, La/Yb) bears strong similarities to that of magmatic systems associated with supergiant porphyry copper deposits, these data may serve to better understand how adakite-like signatures are acquired in fertile arc magmatic systems with metallogenic implications. Files included are: • 2024-018_Chiaradia-et-al_Table-1_Sample-overview: sample overview table with coordinates of and type of analyses carried out on each sample (Table #1) • 2024-018_Chiaradia-et-al_File_1_map: a geological map with location of investigated samples (File #1) • 2024-018_Chiaradia-et-al_File_2_WholeRocks: geochemical and radiogenic isotope data on bulk rocks (File #2). • 2024-018_Chiaradia-et-al_File_3_Pyroxene: contains microprobe and LA-ICP-MS major and trace element analyses of clino- and orthopyroxenes from the CVC and P-T conditions retrieved from clinopyroxene compositions (File #3) • 2024-018_Chiaradia-et-al_File_4_Amphibole: contains microprobe and LA-ICP-MS major and trace element analyses of amphiboles from the CVC and P-T-H2Omelt, fO2 conditions retrieved from amphibole compositions (File #4). • 2024-018_Chiaradia-et-al_File_5_Plagioclase: contains microprobe and LA-ICP-MS major and trace element analyses of plagioclases from the CVC (File #5). • 2024-018_Chiaradia-et-al_File_6_Equilibrium tests: reports the calculations to retrieve pressure and temperature data from clinopyroxene-melt equilibrium and clinopyroxene-only composition (File #6). • 2024-018_Chiaradia-et-al_File_7_CPX_Thermo_Barometry: reports the calculations to obtain P-T conditions from clinopyroxene-orthopyroxene equilibria in the same thin section (File #7). • 2024-018_Chiaradia-et-al_File_8_Cpx_Opx_Thermo_Barometry: reports the equilibrium tests between minerals (clinopyroxene, orthopyroxene, amphibole) and host rock compositions and the P-T values retrieved by clinopyroxene and amphibole analyses that passed the test (File #8). Associated RStudio Scripts are available as https://doi.org/10.5880/fidgeo.2025.010 (Chiarada, 2025).

Geochemical compositions and rheological properties of mantle peridotites from the Zhongba ophiolite

We present comprehensive geochemical compositions and rheological properties of mantle peridotites from the Zhongba ophiolite. The geochemical dataset includes major element compositions of whole rock, as well as major and trace elements of olivine, orthopyroxene, clinopyroxene, and spinel. Water contents of olivine and pyroxenes are also provided. In addition, electron backscattered diffraction (EBSD) data includes calculated stress and detailed profiles. Analytical methods and supplementary figures are included to clearly present the dataset.

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