Other language confidence: 0.996910378113039
This data set is the source of my doctoral thesis and of three resulting publications. Through whole rock geochemistry of selected samples and microprobe and geochronological analyses of key minerals, formerly selected by extensive microscopical studies, standard geothermobarometry and modelling was applied. It has been shown that metamorphic rocks, in particular, the eclogites of the northern Kaghan Valley, Pakistan, were buried to depths of 140-100 km (36-30 kbar) at 790-640°C. Subsequently, cooling during decompression (exhumation) towards 40-35 km (17-10 kbar) and 630-580°C has been superseded by a phase of reheating to about 720-650°C at roughly the same depth before final exhumation has taken place. In the southern-most part of the Kaghan Valley, amphibolite facies assemblages with formation conditions similar to the deduced reheating phase indicate a juxtaposition of both areas after the eclogite facies stage and thus a stacking of Indian Plate units. Radiometric dating of zircon, titanite and rutile by U-Pb and amphibole and micas by Ar-Ar reveal peak pressure conditions at 47-48 Ma. With a maximum exhumation rate of 14 cm/a these rocks reached the crust-mantle boundary at 40-35 km within 1 Ma. Subsequent exhumation (46-41 Ma, 40-35 km) decelerated to ca. 1 mm/a at the base of the continental crust but rose again to about 2 mm/a in the period of 41-31 Ma, equivalent to 35-20 km. Apatite fission track (AFT) and (U-Th)/He ages from eclogites, amphibolites, micaschists and gneisses yielded moderate Oligocene to Miocene cooling rates of about 10°C/Ma in the high altitude northern parts of the Kaghan Valley using the mineral-pair method. AFT ages are of 24.5±3.8 to 15.6±2.1 Ma whereas apatite (U-Th)/He analyses yielded ages between 21.0±0.6 and 5.3±0.2 Ma. The southern-most part of the Valley is dominated by younger late Miocene to Pliocene apatite fission track ages of 7.6±2.1 and 4.0±0.5 Ma that support earlier tectonically and petrologically findings of a juxtaposition and stack of Indian Plate units. As this nappe is tectonically lowermost, a later distinct exhumation and uplift driven by thrusting along the Main Boundary Thrust is inferred. Out of this geochemical, petrological, isotope-geochemical and low temperature thermochronology investigations it was concluded that the exhumation was buoyancy driven and caused an initial rapid exhumation: exhumation as fast as recent normal plate movements (ca. 10 cm/a). As the exhuming units reached the crust-mantle boundary the process slowed down due to changes in buoyancy. Most likely, this exhumation pause has initiated the reheating event that is petrologically evident (e.g. glaucophane rimmed by hornblende, ilmenite overgrowth of rutile). Late stage processes involved widespread thrusting and folding with accompanied regional greenschist facies metamorphism, whereby contemporaneous thrusting on the Batal Thrust (seen sometimes equivalent to the MCT) and back sliding of the Kohistan Arc along the inverse reactivated Main Mantle Thrust caused final exposure of these rocks. Similar circumstances have been seen at Tso Morari, Ladakh, India, 200 km further east where comparable rock assemblages occur. In conclusion, as exhumation was already done well before the initiation of the monsoonal system, climate dependent effects (erosion) appear negligible in comparison to far-field tectonic effects. Thus, the channel flow model is not applicable for this part of the Himalayas.
Kamafugites are 'exotic igneous rocks' with mineralogical and chemical compositions that differ from those observed in common magmas. Despite their importance, kamafugites are still a poorly constrained topic and they lack a general petrological model due to their variable petrographic, geochemical and isotopic features. A detailed comparison among kamafugites is necessary to obtain a deeper understanding of the processes involved in their petrogenesis and of their strongly metasomatised mantle sources. Therefore, this data publication doesn’t only provide new geochemical and isotopic data from kamafugites, but a comprehensive data compilation for kamafugite samples in the Western branch of the East Africa Rift (WEAR) in Uganda and Democratic Republic of Congo, the Intra-Apennine Province (IAP), as well as for the Alto Paranaiba (APIP) and Goiás (GAP) provinces in Brazil. 97 kamafugite whole-rock data for the WEAR, 42 for IAP and 51 for APIP and GAP have been collected and compared to highlight similarities and differences, aiming to reconstruct their petrogenesis. The new data in this data publication results from work conducted at Laboratory of Geochronology and Radiogenic Isotope Geochemistry - Pisa1 (IGG-CNR, Italy) supported by WP3 ILGE - MEET project, PNRR - EU Next Generation Europe program, MUR grant number D53C22001400005.
Eudialyte and eudialyte-group minerals (EGM) are unique tracers of peralkaline silica-undersaturated melts. They receive global interest as potential resources for high-field-strength elements (HFSE) (e. g. Zr, Nb, Ta, and rare-earth elements; REE), i. e. critical materials for modern technologies. The main condition for magmatic crystallization of eudialyte and EGM is that the concentration of Zr in parental melt should reach the saturation level. Thus, the solubility of eudialyte was studied in the system at temperatures between 750 and 1000 °C and pressures of 100 and 200 MPa. Liquid phases in run products are eudialyte, parakeldyshite and albite. Eudialyte is stable between 750 and 900 °C, and decomposes to parakeldyshite between 900 and 1000°C. Eudialyte crystallization in dry peralkaline silica-undersaturated melt at 750 and -850 °C requires minimum 0.2-0.22 wt.% ZrO2 in the melt. In melts with high amounts of dissolved H2O the saturation level in within the same temperature interval is much higher, at 1.1-2.85 wt.% ZrO2. Thus, peralkaline melts should be dry to crystallize EGM at ZrO2 concentrations between 0.2 and 0.3 wt.%. LA-ICP-MS results show that REEs and HFSEs are strongly compatible with eudialyte as the eudialyte-melt distribution coefficients (D) vary from 2 to 90. Light REEs and especially La tend to have lower D values than heavy REEs. The data reflect that the concentrations of REEs and HFSEs in the eudialyte solid solution are mainly determined by the Zr concentrations in the melt: the lowest partition coefficients are observed in experiments with the highest eudialyte solubility, i.e., in experiments at high temperature and with H2O content This data report is the supplement to the publication (Nikolenko et al., 2024, in prep.). This study presents a combined experimental research, EPMA and LA ICP-MS studies. This document describes the LA-ICP-MS analytical methods, sample preparation and the in-situ LA-ICP-MS element composition of eudialyte and peralkaline silica-undersaturated melts. Eudialyte, which was used in experiments is a natural mineral, that had been collected from a pegmatite body on mount Eveslogchorr in the Khibina Massif, Kola Peninsula, Russia. Eudialyte crystals were crushed in a mortar and clear, inclusion-free fragments were hand-picked under a binocular. Three synthetic glasses with variable Na-Al molar ratios were prepared from finely ground mixtures of silica (p.a., Merck®), aluminium oxide (γ-phase, 99.97%, 3 μm powder, Alfa Aesar®), and sodiumcarbonate (anhydrous, p.a., Merck®). The glasses were synthesized by sintering starting mixtures in a platinum crucible first at 900 °C for 1 hour, then crushing of the sintered material and remelting it two or three times at 1100-1200 °C for about 2 hours, with intermediate quenching in cold water and grinding the crushed glass fragments to the grain size of less than 1 mm. Mixtures of the Khibina eudialyte and one of the synthetic glasses were ground in agate mortar to fine powders under acetone, dried at 100 °C for 2 hours, loaded into platinum capsules (outer and inner diameters 4.4 and 4.0 mm respectively) and welded shut. In some runs, distilled water (Merck, Suprapur®) was added to the starting charges before welding.
The data package encompasses field data of clastic and organic sediment, river width and flow velocities of six river transects along the Rio Bermejo, Argentina. The laboratory data entails long-chain n-alkanes and d2H and d13C values of organic matter (soil, deposited sediment, suspended sediment (published by Repasch et al., 2020), leaf litter, floating organic matter, and bedload organic matter from the Rio Bermejo catchment. It further contains the bedload organic matter and estimated bedload organic carbon fluxes of six river transects along the Rio Bermejo. Fluvial transport of organic carbon from the terrestrial biosphere to the oceans is an important term in the global carbon cycle. Traditionally, the long-term burial flux of fluvial particulate organic carbon (POC) is estimated using river suspended sediment flux; however, organic carbon can also travel in river bedload as coarse particulate organic matter (POMBed). Estimates of fluvial POC export to the ocean are highly uncertain because few studies document POMbed sources, flux and evolution during long-distance fluvial transport from uplands to ocean basins. This knowledge gap limits our ability to determine the global terrestrial organic carbon burial flux. In this study we investigate the flux, sources and transformations of POMBed during fluvial transport over a ~1300 km long reach of the Rio Bermejo, Argentina, which has no tributary inputs. To constrain sourcing of POMBed, we analysed the composition and stable hydrogen and carbon isotope ratios (δ2H, δ13C) of plant wax biomarkers from POMBed at six locations along the Rio Bermejo, and compared this to samples of suspended sediment, soil, leaf litter and floating organic debris (POMfloat) from both the lowland and headwater river system. Across all samples, we found no discernible differences in n-alkane average chain length or nC29 δ13C, indicting a common origin for all sampled POMBed. We define three potential POMBed sources: Coarse organic debris we sampled at distinct elevations in the catchment: floodplain leaf litter, headwater leaf litter, and headwater POMfloat. We aim to understand the mixing range of the widely spread POMBed. We determine the range of a possible POMBed mixing signal of the sources within the geochemical parameters, and in addition, determine potential missing POMBed sources, using a mixing-space model developed by (Smith et al., 2013). Leaf litter and POMfloat nC29 δ2H values decrease with elevation, making it a useful proxy for POMBed source elevation. Biomarker δ2H values suggest that POMBed is a mix of distally-derived headwater and locally-recruited floodplain sources at all sampling locations. These results indicate that POMBed can be preserved during transport through lowland rivers for hundreds of kilometres. However, the POMBed flux decreases with increasing transport distance, suggesting mechanical comminution of these coarse organic particles, and progressive transfer into the suspended load. Our provisional estimates suggest that the carbon flux from POMBed comprises less than 1 percent of the suspended load POC flux in the Rio Bermejo. While this represents a small portion of the river POC flux, this coarse, high density material likely has a higher probability of deposition and burial in sedimentary basins, potentially allowing it to be more effective in long-term CO2 drawdown relative to fine suspended particles. Because the rate and ratio of POMBed transport versus comminution likely varies across tectonic and climatic settings, additional research is needed to determine the importance of POMBed in the global carbon cycle.
In autumn 2023, an expedition to Malawi was undertaken within the framework of the research project “CRM-geothermal”. Within „CRM-geothermal“ we are looking for an environmentally friendly co-production of critical raw materials together with the provision of geothermal energy. In the East African Rift System (EARS), high levels of rare earth elements (REE), Sr, Ba and Mg are expected in waters and solids in areas with alkaline volcanic rocks, while other critical elements, including helium, have been sought in other localities. In particular, the eastern branch is the most juvenile sector and has increased geothermal potential related to hot fluids migrating along permeable faults. Malawi was traversed along the eastern arm of the EARS from north to south to collect gas, water, rock and sediment samples associated with natural hot springs. On site, physical and chemical parameters were measured in-situ and documented together with the geology, infrastructure and domestic use of the hot site. Detailed measurements were carried out in different labs in Potsdam and Bremen.
All datasets provided in the operational dataset (Heubeck et al., 2024) of the ICDP project BASE (ICDP 5069) consist of metadata, data and/or images. Here, a summary of explanations of the tables, data and images exported from the database of the project (mDIS BASE) are given and are complemented by additional information on data from measurements done in the laboratory prior to the sampling party. Finally, the sampling data from the first two sampling parties are added. Some basic definitions of identifiers used in ICDP, depths corrections and measurements are also introduced. The BASE (Barberton Archean Surface Environments) scientific drilling project focused on recovering unweathered continuous core through strata of the Paleoarchean Moodies Group (ca. 3.2 Ga), central Barberton Greenstone Belt (BGB), South Africa. They comprise some of the oldest well-preserved sedimentary strata on Earth, deposited within only a few million years in alluvial, fluvial, coastal-deltaic, tidal, and prodeltaic settings; they represent a very-high-resolution record of Paleoarchean surface conditions and processes. Moodies Group strata consist of polymict conglomerates, widespread quartzose, lithic and arkosic sandstones, siltstones, shales, and rare BIFs and jaspilites, interbedded with tuffs and several thin lavas. This report describes operations from preparations to the sampling workshop and complements the related scientific report. Eight inclined boreholes between 280 and 495 m length, drilled during November 2021 through July 2022, obtained a total of 2903 m of curated core of variable quality through steeply to subvertically dipping, in part overturned stratigraphic sections. All drilling objectives were reached. Boreholes encountered a variety of conglomerates, diverse and abundant, mostly tuffaceous sandstones, rhythmically laminated shale-siltstone and banded-iron formations, and several horizons of early-diagenetic sulfate concretions. Oxidative weathering reached far deeper than expected; fracturing was more intense, and BIFs and jaspilites were thicker than anticipated. Two km-long mine adits and a water tunnel, traversing four thick stratigraphic sections within the upper Moodies Group in the central BGB, were also sampled. All boreholes were logged by geophysical instruments. Core was processed (oriented, slabbed, photographed, described, and archived) in a large, publicly accessible hall in downtown Barberton. An exhibition provided background explanations for visitors and related the drilling objectives to the recently established Barberton-Makhonjwa Mountains World Heritage Site. A substantial education, outreach and publicity program addressed the information needs of the local population and of local and regional stakeholders.
A compilation of 90,688 published radiometric dates for sedimentary rocks from the South American Andes and adjacent parts of South America have been tabulated for access by researchers via GEOROC Expert Datasets. The compilation exists as a spreadsheet for access via MS Excel, Google Sheets, and other spreadsheet applications. Initial igneous compilations were utilized in two publications by the author, Pilger (1981, 1984). The compilations have been added to in subsequent years with the metamorphic and sedimentary compilations separated in the last few years. Locations in latitude and longitude are largely taken from the original source, if provided, with UTM locations maintained and converted; in some cases, sample locations were digitized from electronic maps if coordinates were otherwise not available. Analytical results are not included to prevent the files from becoming too large. The existing compilation incorporates compilations by other workers in smaller regions of the Andes. References to original and compilation sources are included. While I am updating reconstructions of the South American and Nazca/Farallon plates, incorporating recent studies in the three oceans, for comparison with the igneous dates for the past 80 m. y., it is hoped that the spreadsheets will be of value to other workers. Reliability: In most cases the data have been copy/pasted from published or appendix tables. In a few cases, the location has been digitized from published maps; the (equatorial equidistant) maps were copied into Google Earth and positioned according to indicated coordinates, with locations digitized and copied/pasted into the spreadsheet. (It is possible that published maps are conventional Mercator-based, even if not so identified, rather than either equatorial equidistant or Universal Transverse Mercator; this can be a source of error in location. For UTMs, the errors should be minor.) Duplicates are largely recognized by equivalent IDs, dates, and uncertainties. Where primary sources have been accessed, duplicate data points in compilations are deleted. (Analytic data are NOT included.) This compilation is part of a series. Companion compilations of radiometric dates from igneous and metamorphic rocks are available at https://doi.org/10.5880/digis.e.2023.005 and https://doi.org/10.5880/digis.e.2023.007, respectively.
The dataset includes Ruthenium and Tungsten isotope data for mafic to ultramafic lava associated with the Hawaii, Réunion, Galápagos and Iceland plume systems. The data is supplemented by Ru isotope data for reference materials (OREAS 684) picrite derived from the upper mantle (Gönnern Quarry, Hessia) lherzolite preidotites (Eifel) and Eoarchean dunites (Isua, Greenland). The data are supplementary to: Messling, Nils; Willbold, Matthias; Kallas, Leander; Elliott, Tim; Fitton, J. Godfrey; Müller, Thomas; Geist, Dennis (submitted) Core leakage revealed by Ru and W isotope systematics in ocean island basalts. Submitted to Nature
A compilation of 29,574 published radiometric dates for metamorphic rocks from the South American Andes and adjacent parts of South America have been tabulated for access by researchers via GEOROC Expert Datasets. The compilation exists as a spreadsheet for access via MS Excel, Google Sheets, and other spreadsheet applications. Initial igneous compilations were utilized in two publications by the author, Pilger (1981, 1984). The compilations have been added to in subsequent years with the metamorphic and sedimentary compilations separated in the last few years. Locations in latitude and longitude are largely taken from the original source, if provided, with UTM locations maintained and converted; in some cases, sample locations were digitized from electronic maps if coordinates were otherwise not available. Analytical results are not included to prevent the files from becoming too large. The existing compilation incorporates compilations by other workers in smaller regions of the Andes. References to original and compilation sources are included. While I am updating reconstructions of the South American and Nazca/Farallon plates, incorporating recent studies in the three oceans, for comparison with the igneous dates for the past 80 m. y., it is hoped that the spreadsheets will be of value to other workers. Reliability: In most cases the data have been copy/pasted from published or appendix tables. In a few cases, the location has been digitized from published maps; the (equatorial equidistant) maps were copied into Google Earth and positioned according to indicated coordinates, with locations digitized and copied/pasted into the spreadsheet. (It is possible that published maps are conventional Mercator-based, even if not so identified, rather than either equatorial equidistant or Universal Transverse Mercator; this can be a source of error in location. For UTMs, the errors should be minor.) Duplicates are largely recognized by equivalent IDs, dates, and uncertainties. Where primary sources have been accessed, duplicate data points in compilations are deleted. (Analytic data are NOT included.) This compilation is part of a series. Companion compilations of radiometric dates from igneous and sedimentary rocks are available at https://doi.org/10.5880/digis.e.2023.005 and https://doi.org/10.5880/digis.e.2023.006, respectively.
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