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The main objective of the work package 2 of the REFLECT project is to characterise relevant fluid properties and their reactions for saline fluids (type C). One of the specific goals was to collect fluid samples from several saline fluids from geothermal sites across Europe, determine their properties, and thus contribute to the Fluid Atlas (WP3). Additionally, the REFLECT team will compare those field data with data from lab experiments performed at near natural conditions. Samples of type C fluids were taken from several sites in Germany, Austria, Belgium and the Netherlands. The samples were analysed for major and minor ions, dissolved gases and isotopes. On 10th of May 2021, two thermal water samples were taken by TNO before and after the heat exchanger at the geothermal site Heemskerk in the Netherlands. The samples sent to Hydroisotop were analysed for their hydrochemical composition, heavy metal and dissolved organic carbon (DOC) content and stable isotopes (18O, 2H, 13C-DIC). It should be noted that the pH measured in the laboratory diverges from previously observed pH values which in the past have not been reported below 5,4. Concentrations of major ions had initially been reported too low but re-measurement of the samples yielded values in ranges that had previously been recorded. However, the concentraton of Lithium is much higher than expected. In order to resolve these uncertainties, the site Heemskerk will be sampled again. The dataset contains analysis results associated with the research project REFLECT. It is a comma separated file (csv) containing the following columns: Location,Country,Description,Laboratory (Lab.),Lab. No.,Sampling date,Spec. electr. conductivity (25 degC) Lab. (muS/cm),pH value Lab.,Temperature Lab. (degC),Alkalinity (pH 4.3) Lab. (mmol/l),Sodium (mg/l),Potassium (mg/l),Calcium (mg/l),Magnesium (mg/l),Ammonium (mg/l),Hydrogen carbonate (mg/l),Chloride (mg/l),Sulphate (mg/l),Nitrate (mg/l),Antimony (mg/l),Barium (mg/l),Fluoride (mg/l),Iodide (mg/l),Lithium (mg/l),Silicon (mg/l),Strontium (mg/l),Aluminium (mg/l),Arsenic (mg/l),Lead (mg/l),Iron total (mg/l),Copper (mg/l),Manganese total (mg/l),Nickel (mg/l),Uranium (mg/l),Zinc (mg/l),DOC (mg/l),Oxygen-18 d18O-H2O (per mille VSMOW),Deuterium d2H-H2O (per mille VSMOW),Deuterium-excess (per mille VSMOW),Carbon-13 d13C-DIC (per mille VPDB). Methods are described in the accompanying deliverable Fluid data of geothermal sites (type C)
The main objective of the work package 2 of the REFLECT project is to characterise relevant fluid properties and their reactions for saline fluids (type C). One of the specific goals was to collect fluid samples from several saline fluids from geothermal sites across Europe, determine their properties, and thus contribute to the Fluid Atlas (WP3). Additionally, the REFLECT team will compare those field data with data from lab experiments performed at near natural conditions. Samples of type C fluids were taken from several sites in Germany, Austria, Belgium and the Netherlands. The samples were analysed for major and minor ions, dissolved gases and isotopes. At the geothermal site Blumau in Austria five thermal water samples were taken by Hydroisotop at the production and injection well, as well as after the heat exchanger on 29th of June 2020. Besides the hydrochemical composition, dissolved gases, the heavy metal content, DOC and stable isotopes (18O, 2H, 13C-DIC) were analysed. Additionally, three thermal water samples were taken by the operator on 09th of March 2021 and sent to Hydroisotop for DOC measurements. The dataset contains analysis results associated with the research project reflect. It is a comma separated file (csv) containing the following columns: Location,Country,Description,Laboratory,Lab No.,Sampling date,Temperature at sampling (degC),Spec. electr. conductivity (25 degC) at sampling,Spec. electr. conductivity (25 degC) Lab. (muS/cm),pH value at sampling,pH value Lab.,Temperature Lab. (degC),Dissolved oxygen content (mg/l),Redox potential (mV),Alkalinity (pH 4.3) Lab. (mmol/l),Sodium (mg/l),Potassium (mg/l),Calcium (mg/l),Magnesium (mg/l),Ammonium (mg/l),Hydrogen carbonate (mg/l),Chloride (mg/l),Sulphate (mg/l),Nitrate (mg/l),Nitrite (mg/l),Antimony (mg/l),Barium (mg/l),Boron (mg/l),Bromide (mg/l),Fluoride (mg/l),Iodide (mg/l),Molybdenum (mg/l),Ortho-phosphate (mg/l),Selenium (mg/l),Strontium (mg/l),Sulphide total (mg/l),Aluminium (mg/l),Arsenic (mg/l),Lead (mg/l),Cadmium (mg/l),Chromium total (mg/l),Cobalt (mg/l),Iron total (mg/l),Copper (mg/l),Nickel (mg/l),Mercury (mg/l),Zinc (mg/l),Tin (mg/l),DOC (mg/l),Hydrogen (Nml/kg),Oxygen (Nml/kg),Nitrogen (Nml/kg),Carbon dioxide (Nml/kg),Methane (Nml/kg),Ethane (Nml/kg),Propane (Nml/kg),Butane (Nml/kg),Pentane (Nml/kg),Ethene (Nml/kg),Propene (Nml/kg),Helium (Nml/kg),Argon (Nml/kg),Sum Gases (Nml/kg),Oxygen-18 d18O-H2O (per mille VSMOW),Deuterium d2H-H2O (per mille VSMOW),Deuterium-excess (per mille VSMOW),Carbon-13 d13C-DIC (per mille VPDB) Methods are described in the accompanying deliverable Fluid data of geothermal sites (type C).
The main objective of the work package 2 of the REFLECT project is to characterise relevant fluid properties and their reactions for saline fluids (type C). One of the specific goals was to collect fluid samples from several saline fluids from geothermal sites across Europe, determine their properties, and thus contribute to the Fluid Atlas (WP3). Additionally, the REFLECT team will compare those field data with data from lab experiments performed at near natural conditions. Samples of type C fluids were taken from several sites in Germany, Austria, Belgium and the Netherlands. The samples were analysed for major and minor ions, dissolved gases and isotopes. Two thermal water samples were taken by Hydroisotop at the production and injection wells in Insheim on 18th of June 2020. The samples were analysed for their hydrochemical composition, heavy metal and dissolved organic carbon (DOC) content, dissolved gases and stable isotopes of water and gas components (18O, 2H, 34S-H2S, 34S-SO4, 18O-SO4, 13C-DIC, 13C-CO2, 13C-CH4, 2H-CH4). Nitrate and a positive redox potential is present in both water samples when reducing conditions would be expected in a deep geothermal well. On-site measurements showed no oxygen present. It is however possible that air contamination during sampling caused some ammonium to oxidize to nitrate. The dataset contains analysis results associated with the research project REFLECT. It is a comma separated file (csv) containing the following columns: Location,Country,Description,Laboratory (Lab.),Lab. No.,Sampling date,Temperature at sampling (degC),Spec. electr. conductivity (25 degC) at sampling (muS/cm),Spec. electr. conductivity (25 degC) Lab. (muS/cm),pH value at sampling,pH value Lab.,Dissolved oxygen content (mg/l),Redox potential (mV),Base capacity (pH 8.2) (mmol/l),Alkalinity (pH 4.3) on site (mmol/l),Alkalinity (pH 4.3) Lab. (mmol/l),Sodium (mg/l),Potassium (mg/l),Calcium (mg/l),Magnesium (mg/l),Ammonium (mg/l),Hydrogen carbonate (mg/l),Chloride (mg/l),Sulphate (mg/l),Nitrate (mg/l),Antimony (mg/l),Barium (mg/l),Bromide (mg/l),Fluoride (mg/l),Iodide (mg/l),Lithium (mg/l),Molybdenum (mg/l),Total phosphate (mg/l),Ortho-phosphate (mg/l),Silicon (mg/l),Strontium (mg/l),Sulphide total (mg/l),Aluminium (mg/l),Arsenic (mg/l),Lead (mg/l),Iron total (mg/l),Copper (mg/l),Manganese total (mg/l),Nickel (mg/l),Uranium (mg/l),Zinc (mg/l),DOC (mg/l),Hydrogen (Nml/kg),Oxygen (Nml/kg),Nitrogen (Nml/kg),Carbon dioxide (Nml/kg),Methane (Nml/kg),Ethane (Nml/kg),Propane (Nml/kg),Butane (Nml/kg),Pentane (Nml/kg),Helium (Nml/kg),Argon (Nml/kg),Sum Gases (Nml/kg),Oxygen-18 d18O-H2O (per mille VSMOW),Deuterium d2H-H2O (per mille VSMOW),Deuterium-excess (per mille VSMOW),Carbon-13 d13C-DIC (per mille VPDB),Sulphur-34 d34S-SO4 (per mille V-CDT),Sulphur-34 d34S-H2S (per mille V-CDT),Oxygen-18 d18O-SO4 (per mille VSMOW),Carbon-13 d13C-CO2 (per mille VPDB),Carbon-13 d13C-CH4 (per mille VPDB),Deuterium d2H-CH4 (per mille VPDB). Methods are described in the accompanying deliverable Fluid data of geothermal sites (type C)
The main objective of the work package 2 of the REFLECT project is to characterise relevant fluid properties and their reactions for saline fluids (type C). One of the specific goals was to collect fluid samples from several saline fluids from geothermal sites across Europe, determine their properties, and thus contribute to the Fluid Atlas (WP3). Additionally, the REFLECT team will compare those field data with data from lab experiments performed at near natural conditions. Samples of type C fluids were taken from several sites in Germany, Austria, Belgium and the Netherlands. The samples were analysed for major and minor ions, dissolved gases and isotopes. At Neustadt-Glewe one thermal water sample was taken by GFZ on June 02, 2021 and sent to Hydroisotop for analysis of main cations, anions, heavy metals, DOC, gases and isotopes (18O, 2H, 18O-SO4, 2H, 13C-DIC, 13C-CO2, 13C-CH4, 13C-CxHy, 2H-CH4, 34S-SO4, 34S-H2S, 2H-CH4). There was too little H2S in sample 363469 to conduct the 34S-H2S measurement. The dataset contains analysis results associated with the research project REFLECT. It is a comma separated file (csv) containing the following columns: Location,Country,Description,Laboratory (Lab.),Lab. No.,Sampling date,Spec. electr. conductivity (25 degC) Lab.,pH value Lab.,Temperature Lab. (degC),Alkalinity (pH 4.3) Lab. (mmol/l),Sodium (mg/l),Potassium (mg/l),Calcium (mg/l),Magnesium (mg/l),Ammonium (mg/l),Hydrogen carbonate (mg/l),Chloride (mg/l),Sulphate (mg/l),Nitrate (mg/l),Antimony (mg/l),Barium (mg/l),Fluoride (mg/l),Iodide (mg/l),Lithium (mg/l),Silicon (mg/l),Strontium (mg/l),Aluminium (mg/l),Arsenic (mg/l),Lead (mg/l),Chromium total (mg/l),Iron total (mg/l),Copper (mg/l),Manganese total (mg/l),Nickel (mg/l),Uranium (mg/l),Zinc (mg/l),DOC (mg/l),Hydrogen (Nml/kg),Oxygen (Nml/kg),Nitrogen (Nml/kg),Carbon dioxide (Nml/kg),Methane (Nml/kg),Ethane (Nml/kg),Propane (Nml/kg),Butane (Nml/kg),Pentane (Nml/kg),Helium (Nml/kg),Argon (Nml/kg),Sum Gases (Nml/kg),Oxygen-18 d18O-H2O (per mille VSMOW),Deuterium d2H-H2O (per mille VSMOW),Deuterium-excess (per mille VSMOW),Carbon-13 d13C-DIC (per mille VPDB),Sulphur-34 d34S-SO4 (per mille V-CDT),Oxygen-18 d18O-SO4 (per mille VSMOW),Carbon-13 d13C-CO2 (per mille VPDB),Carbon-13 d13C-CH4 (per mille VPDB),Deuterium d2H-CH4 (per mille VSMPW),Carbon-13 d13C-C2H6 (per mille VPDB),Carbon-13 d13C-C3H8 (per mille VPDB),Carbon-13 d13C-i-C4H10 (per mille VPDB),Carbon-13 d13C-n-C4H10 (per mille VPDB) Methods are described in the accompanying deliverable Fluid data of geothermal sites (type C) .
The main objective of the work package 2 of the REFLECT project is to characterise relevant fluid properties and their reactions for saline fluids (type C). One of the specific goals was to collect fluid samples from several saline fluids from geothermal sites across Europe, determine their properties, and thus contribute to the Fluid Atlas (WP3). Additionally, the REFLECT team will compare those field data with data from lab experiments performed at near natural conditions. Samples of type C fluids were taken from several sites in Germany, Austria, Belgium and the Netherlands. The samples were analysed for major and minor ions, dissolved gases and isotopes. In order to gain information about the increased methane content (about 65 vol-%) in the gas samples of the Groß Schönebeck production well (GrSk05/05) collected in February 2021 as compared to previous samples in 2010-2018 (10-14 vol-%), three gas samples were sampled by GFZ on 02 March 2021 at the valve at the wellhead when releasing the pressure from the wellhead. Main gas composition was measured by GFZ indicating again predominantly CH4 (63,9-64,2 Vol-%) followed by N2 (30,9 – 31,2 vol.-%) with minor amounts of H2 (3,4 vol-%) and CO2 (0,01-0,04 vol-%). Potential reasons for the increased methane content could be either microbial activity or contribution of fluid / gas from a different source within the reservoir. To determine the origin of methane, therefore, isotope analyses were performed. The samples arrived at Hydroisotop on March 13th 2021 for the analysis of higher hydrocarbons (C2-C5) and their isotopic composition (13C-CO2, 13C -CH4, 13C-CxHy and 2H-CH4). Together with the measured high amounts of higher hydrocarbons (ethane, propane etc.) they indicate a rather thermogenic source of the hydrocarbons. To better clarify the question of the source of methane, additionally, two downhole water samples from two different depths (1500 and 4000 m) were taken by GFZ on 09th and 10th of June 2021 and sent to Hydroisotop for analysis of main cations and anions, heavy metals, trace elements and isotopes (13C-CH4) in July 2021. The water sample composition resembles those of earlier measurements of samples collected in Groß Schönebeck (e.g. Regenspurg et al., 2010). However, since the well had not been in operation for a while a depth differentiation between the sample from 4000 m and the one from 1500 m is obvious. This was already visible by the black precipitate observed in the 4000 m sample, whereas the sample at 1500 m showed da reddish precipitate of presumably iron oxides. It should be noted that the nitrate content of the water samples is unusually high since reducing conditions are expected. This could have been caused by air contact of the sample and subsequent oxidation. Furthermore, a reduced silicon content shows in sample 365871 compared to sample 365870. Given the high temperature of the well, the higher silicon content is more plausible. The dataset contains analysis results associated with the research project REFLECT. It is a comma separated file (csv) containing the following columns: Location,Country,Description,Laboratory (Lab.),Lab. No.,Sampling date,Sodium (mg/l),Potassium (mg/l),Calcium (mg/l),Magnesium (mg/l),Chloride (mg/l),Sulphate (mg/l),Nitrate (mg/l),Antimony (mg/l),Barium (mg/l),Bromide (mg/l),Fluoride (mg/l),Iodide (mg/l),Lithium (mg/l),Silicon (mg/l),Strontium (mg/l),Aluminium (mg/l),Arsenic (mg/l),Lead (mg/l),Copper (mg/l),Manganese total (mg/l),Nickel (mg/l),Uranium (mg/l),Zinc (mg/l),Ethane (vpm),Propane (vpm),i-Butane (vpm),n-Butane (vpm),i-Pentane (vpm),n-Pentane (vpm),Ethene (vpm),Propene (vpm),1-Butene (vpm),Carbon-13 d13C-CO2 (per mille VPDB),Carbon-13 d13C-CH4 (per mille VPDB),Deuterium d2H-CH4 (per mille VPDB),Carbon-13 d13C-C2H6 (per mille VPDB),Carbon-13 d13C-C3H8 (per mille VPDB),Carbon-13 d13C-i-C4H10 (per mille VPDB),Carbon-13 d13C-n-C4H10 (per mille VPDB) Methods are described in the accompanying deliverable Fluid data of geothermal sites (type C).
This data publication is supplementary to the study on headwall erosion rates at Glacier d'Otemma in Switzerland, by Wetterauer et al. (2022). Debris on glacier surfaces stems from steep bedrock hillslopes that tower above the ice, so-called headwalls. Recently, rock walls in high-alpine glacial environments experience increased destabilization due to climate warming. Since supraglacial debris alters the melt behaviour of the ice underneath, increased headwall erosion and debris delivery to glacier surfaces will modify glacial mass balances. Therefore, we expect that the response of glaciers to climate change is likely linked to how headwall erosion responds to climate change. As headwall debris is deposited on the ice surface of valley glaciers it is passively transported downglacier, both supra- and englacially. Where two glaciers join, debris along their margins is merged to form medial moraines. Since medial moraine debris tends to be older downglacier, systematic downglacier-sampling of medial moraine debris and the measurement of in situ-produced cosmogenic 10Be concentrations ([10Be]) hold the potential to assess long-term (>10^2-10^4 yrs) headwall erosion rates through time. However, to obtain the cosmogenic signals of headwall erosion, [10Be] within supraglacial debris need to be corrected for glacial transport time, as cosmogenic nuclides continue to accumulate during exposure and transport. This additional 10Be accumulation during debris transport can be accounted for by simple downglacier debris trajectory modelling. Providing our 10Be dataset together with detailed information on our 1-D modelling approach is the main objective of this data publication. The data is presented as one single xlsx-file with three different tables. A detailed description of the sample processing and the debris trajectory model are provided in the data description file of this data publication. For more information see our study Wetterauer et al. (2022).
We provide geochemical data for three sites that define a gradient of erosion rates – an “erodosequence”. These sites are the Swiss Central Alps, a rapidly-eroding post-glacial mountain belt; the Southern Sierra Nevada, USA, eroding at moderate rates; and the slowly-eroding tropical Highlands of central Sri Lanka. Specifically, we provide silicon isotope ratios and germanium/silicon ratios and the major element composition of 1) rock, 2) saprolite, 3) soil, 4) plants, 5) river dissolved loads, 6) the soil and saprolite amorphous silica fraction (accessed with a NaOH leach), and 7) the soil and saprolite clay-size fraction (isolated with a differential settling protocol). These data serve two purposes. First, they allow us to improve understanding of the controls on silicon isotopes and germanium/silicon ratios in the 'Critical Zone'. Specifically, we can quantify the fractionation factors (for silicon isotopes) and the exchange coefficients (for germanium/silicon ratios), for secondary mineral precipitation and for biological uptake. Secondly, we can use mass-balance approaches to quantify the partitioning of silicon - a nutrient, and a major rock-forming element - among secondary minerals, plant material, and solutes. All samples are assigned with International Geo Sample Numbers (IGSN), a globally unique and persistent Identifier for physical samples. The IGSNs are provided in the data tables and link to a comprehensive sample description.
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