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Kaghan Valley, Pakistan: metamorphic rocks, their chemistry and age

This data set is the source of my doctoral thesis and of three resulting publications. Through whole rock geochemistry of selected samples and microprobe and geochronological analyses of key minerals, formerly selected by extensive microscopical studies, standard geothermobarometry and modelling was applied. It has been shown that metamorphic rocks, in particular, the eclogites of the northern Kaghan Valley, Pakistan, were buried to depths of 140-100 km (36-30 kbar) at 790-640°C. Subsequently, cooling during decompression (exhumation) towards 40-35 km (17-10 kbar) and 630-580°C has been superseded by a phase of reheating to about 720-650°C at roughly the same depth before final exhumation has taken place. In the southern-most part of the Kaghan Valley, amphibolite facies assemblages with formation conditions similar to the deduced reheating phase indicate a juxtaposition of both areas after the eclogite facies stage and thus a stacking of Indian Plate units. Radiometric dating of zircon, titanite and rutile by U-Pb and amphibole and micas by Ar-Ar reveal peak pressure conditions at 47-48 Ma. With a maximum exhumation rate of 14 cm/a these rocks reached the crust-mantle boundary at 40-35 km within 1 Ma. Subsequent exhumation (46-41 Ma, 40-35 km) decelerated to ca. 1 mm/a at the base of the continental crust but rose again to about 2 mm/a in the period of 41-31 Ma, equivalent to 35-20 km. Apatite fission track (AFT) and (U-Th)/He ages from eclogites, amphibolites, micaschists and gneisses yielded moderate Oligocene to Miocene cooling rates of about 10°C/Ma in the high altitude northern parts of the Kaghan Valley using the mineral-pair method. AFT ages are of 24.5±3.8 to 15.6±2.1 Ma whereas apatite (U-Th)/He analyses yielded ages between 21.0±0.6 and 5.3±0.2 Ma. The southern-most part of the Valley is dominated by younger late Miocene to Pliocene apatite fission track ages of 7.6±2.1 and 4.0±0.5 Ma that support earlier tectonically and petrologically findings of a juxtaposition and stack of Indian Plate units. As this nappe is tectonically lowermost, a later distinct exhumation and uplift driven by thrusting along the Main Boundary Thrust is inferred. Out of this geochemical, petrological, isotope-geochemical and low temperature thermochronology investigations it was concluded that the exhumation was buoyancy driven and caused an initial rapid exhumation: exhumation as fast as recent normal plate movements (ca. 10 cm/a). As the exhuming units reached the crust-mantle boundary the process slowed down due to changes in buoyancy. Most likely, this exhumation pause has initiated the reheating event that is petrologically evident (e.g. glaucophane rimmed by hornblende, ilmenite overgrowth of rutile). Late stage processes involved widespread thrusting and folding with accompanied regional greenschist facies metamorphism, whereby contemporaneous thrusting on the Batal Thrust (seen sometimes equivalent to the MCT) and back sliding of the Kohistan Arc along the inverse reactivated Main Mantle Thrust caused final exposure of these rocks. Similar circumstances have been seen at Tso Morari, Ladakh, India, 200 km further east where comparable rock assemblages occur. In conclusion, as exhumation was already done well before the initiation of the monsoonal system, climate dependent effects (erosion) appear negligible in comparison to far-field tectonic effects. Thus, the channel flow model is not applicable for this part of the Himalayas.

Detrital age spectra and petrological analysis of gravel-size clasts of the Oligocene-early Miocene glaciomarine sediments of the DSDP drilling Site 270, Central Ross Sea, Antarctica

This data-set contains provenance detrital data from the glacimarine sequence of Deep Sea Drilling Project Site 270. The 270 site was cored on a flank of the Central High in the central Ross Sea and recovered a thick Oligocene to lower Miocene glacimarine sequence, overlain by ~20 m of Pliocene to Recent strata. This site provides important temporal constraints on regional stratigraphy and insights into late Oligocene to early Miocene ice sheet dynamics. We analyzed eight detrital samples of glaciomarine sediments distributed along the core and two from the basement rocks recovered during coring, by using an integrated single-grain provenance approach. This multi-proxy provenance study employs conventional U-Pb detrital zircon dating integrated with apatite U-Pb and fission-track dating and trace element analysis of detrital apatite and clast petrology. The data-set suggests a general evolution from local erosion due to small ice caps to far-travelled glacial detritus responding to the continuous sea floor subsidence. The detrital age spectra of a late Oligocene diamicitite is consistent with far travelled grains from southern West Antarctica (WA), suggesting an expansion of the WA ice sheet that should be the oldest and first evidence of ice sheet growth on the WA.

Radiometric Dates from the South American Andes and Adjacent Areas: A Compilation - part 2 sedimentary rocks

A compilation of 90,688 published radiometric dates for sedimentary rocks from the South American Andes and adjacent parts of South America have been tabulated for access by researchers via GEOROC Expert Datasets. The compilation exists as a spreadsheet for access via MS Excel, Google Sheets, and other spreadsheet applications. Initial igneous compilations were utilized in two publications by the author, Pilger (1981, 1984). The compilations have been added to in subsequent years with the metamorphic and sedimentary compilations separated in the last few years. Locations in latitude and longitude are largely taken from the original source, if provided, with UTM locations maintained and converted; in some cases, sample locations were digitized from electronic maps if coordinates were otherwise not available. Analytical results are not included to prevent the files from becoming too large. The existing compilation incorporates compilations by other workers in smaller regions of the Andes. References to original and compilation sources are included. While I am updating reconstructions of the South American and Nazca/Farallon plates, incorporating recent studies in the three oceans, for comparison with the igneous dates for the past 80 m. y., it is hoped that the spreadsheets will be of value to other workers. Reliability: In most cases the data have been copy/pasted from published or appendix tables. In a few cases, the location has been digitized from published maps; the (equatorial equidistant) maps were copied into Google Earth and positioned according to indicated coordinates, with locations digitized and copied/pasted into the spreadsheet. (It is possible that published maps are conventional Mercator-based, even if not so identified, rather than either equatorial equidistant or Universal Transverse Mercator; this can be a source of error in location. For UTMs, the errors should be minor.) Duplicates are largely recognized by equivalent IDs, dates, and uncertainties. Where primary sources have been accessed, duplicate data points in compilations are deleted. (Analytic data are NOT included.) This compilation is part of a series. Companion compilations of radiometric dates from igneous and metamorphic rocks are available at https://doi.org/10.5880/digis.e.2023.005 and https://doi.org/10.5880/digis.e.2023.007, respectively.

Detrital zircon (U-Th)/He thermochronometry data from the Leones Valley, Patagonian Andes

The data presented here were produced to study glacial and glacio-fluvial catchment erosion using 'tracer thermochronology' where detrital downstream samples can be used to infer the source elevation sectors of sediments when integrated with known surface bedrock ages from the catchment. For the first time, our study used the zircon (U-Th)/He (ZHe) method as tracer thermochronometer. The samples come from the Leones Valley at the northeastern flank of the Northern Patagonian Icefield, Chile (46.7° S) This data set comprises ZHe analytical results from (i) six detrital samples of different depositional age and grain size (622 single-grain analyses in total), and (ii) two previously analyzed (Andrić-Tomašević et al., 2021) bedrock samples (22 single-grain analyses in total), as well as grain size measurements and lithology identification of two of the detrital samples (two pebble samples with 262 and 211 pebbles, respectively). Data are provided in 10 tab-delimited text files. The full description of the data and methods is provided in the data description file.

Compilation of global Archean and Paleoproterozoic sanukitoid geochemical data

Sanukitoids, also referred to as high-Mg diorites, are a distinctive type of igneous rock from the late Archean-early Proterozoic, and are characterised by enrichment in both compatible elements (e.g. Mg, Ni, Cr) and incompatible elements (e.g. Ba, Sr, light rare earth elements). Their geochemistry is typically interpreted as recording petrogenesis of their parental magmas via interaction between mantle peridotite and recycled crust-derived component (e.g. metabasite melts, sediment melts, aqueous fluids), and is often considered to be "transitional" between that of Archean sodic tonalite-trondhjemite-granodiorite (TTG) suites and post-Archean potassic granites. This dataset presents a global compilation of all Archean-Paleoproterozoic rocks that have been described as "sanukitoid" in published literature, and consists of over 3600 individual samples. Whole rock major and trace element concentrations, radiogenic isotope compositions and stable isotope compositions are compiled in the dataset alongside reported magmatic ages of the samples. The dataset is provided both as an Excel workbook divided by craton (file: 2025-003_Spencer-et-al_Sanukitoid-Compilation.xlsx) and as a single CSV file (file: 2025-003_Spencer-et-al_Sanukitoid-Compilation.csv). Sanukitoid magmatism has been described on almost every Archean craton globally. Most reported sanukitoid magmatism occurred during the late Mesoarchean-Neoarchean (2.95 - 2.5 Ga), with another peak in sanukitoid magmatism in the mid-Paleoproterozoic (2.2 - 2.0 Ga). Older sanukitoid occurrences dating back to the Paleoarchean (>3.2 Ga) are also described in the literature.

Radiometric Dates from the South American Andes and Adjacent Areas: A Compilation - part 3 metamorphic rocks

A compilation of 29,574 published radiometric dates for metamorphic rocks from the South American Andes and adjacent parts of South America have been tabulated for access by researchers via GEOROC Expert Datasets. The compilation exists as a spreadsheet for access via MS Excel, Google Sheets, and other spreadsheet applications. Initial igneous compilations were utilized in two publications by the author, Pilger (1981, 1984). The compilations have been added to in subsequent years with the metamorphic and sedimentary compilations separated in the last few years. Locations in latitude and longitude are largely taken from the original source, if provided, with UTM locations maintained and converted; in some cases, sample locations were digitized from electronic maps if coordinates were otherwise not available. Analytical results are not included to prevent the files from becoming too large. The existing compilation incorporates compilations by other workers in smaller regions of the Andes. References to original and compilation sources are included. While I am updating reconstructions of the South American and Nazca/Farallon plates, incorporating recent studies in the three oceans, for comparison with the igneous dates for the past 80 m. y., it is hoped that the spreadsheets will be of value to other workers. Reliability: In most cases the data have been copy/pasted from published or appendix tables. In a few cases, the location has been digitized from published maps; the (equatorial equidistant) maps were copied into Google Earth and positioned according to indicated coordinates, with locations digitized and copied/pasted into the spreadsheet. (It is possible that published maps are conventional Mercator-based, even if not so identified, rather than either equatorial equidistant or Universal Transverse Mercator; this can be a source of error in location. For UTMs, the errors should be minor.) Duplicates are largely recognized by equivalent IDs, dates, and uncertainties. Where primary sources have been accessed, duplicate data points in compilations are deleted. (Analytic data are NOT included.) This compilation is part of a series. Companion compilations of radiometric dates from igneous and sedimentary rocks are available at https://doi.org/10.5880/digis.e.2023.005 and https://doi.org/10.5880/digis.e.2023.006, respectively.

Radiometric Dates from the South American Andes and Adjacent Areas: A Compilation - part 1 igenous rocks

A compilation of 39,070 published radiometric dates for igneous rocks from the South American Andes and adjacent parts of South America have been tabulated for access by researchers via GEOROC Expert Datasets. The compilation exists as a spreadsheet for access via MS Excel, Google Sheets, and other spreadsheet applications. Initial igneous compilations were utilized in two publications by the author, Pilger (1981, 1984). The compilations have been added to in subsequent years with the metamorphic and sedimentary compilations separated in the last few years. Locations in latitude and longitude are largely taken from the original source, if provided, with UTM locations maintained and converted; in some cases, sample locations were digitized from electronic maps if coordinates were otherwise not available. Analytical results are not included to prevent the files from becoming too large. The existing compilation incorporates compilations by other workers in smaller regions of the Andes. References to original and compilation sources are included. While I am updating reconstructions of the South American and Nazca/Farallon plates, incorporating recent studies in the three oceans, for comparison with the igneous dates for the past 80 m. y., it is hoped that the spreadsheets will be of value to other workers. Reliability: In most cases the data have been copy/pasted from published or appendix tables. In a few cases, the location has been digitized from published maps; the (equatorial equidistant) maps were copied into Google Earth and positioned according to indicated coordinates, with locations digitized and copied/pasted into the spreadsheet. (It is possible that published maps are conventional Mercator-based, even if not so identified, rather than either equatorial equidistant or Universal Transverse Mercator; this can be a source of error in location. For UTMs, the errors should be minor.) Duplicates are largely recognized by equivalent IDs, dates, and uncertainties. Where primary sources have been accessed, duplicate data points in compilations are deleted. (Analytic data are NOT included.) This compilation is part of a series. Companion compilations of radiometric dates from sedimentary and metamorphic rocks are available at https://doi.org/10.5880/digis.e.2023.006 and https://doi.org/10.5880/digis.e.2023.007, respectively.

Compilation of global Archean high-Sr tonalite-trondhjemite-granodiorite (TTG) geochemical data

Tonalite-trondhjemite-granodiorite (TTG) suites are the main constituent of Archean (4-2.5 Ga) continental crust. High-Sr TTGs are a subgroup of "high-pressure" TTGs characterised by very high Sr concentrations (>500 ppm, but often >700 ppm) and Sr/Y (>100), in addition to K2O/N2O<0.5, Yb<0.4 ppm and La/Yb>60 at SiO2≈70 wt%. High-Sr TTGs may have formed via fractional crystallisation of metasomatised mantle-derived sanukitoid magmas, in contrast to the dominant petrogenetic model for "high-pressure" TTGs involving metabasite partial melting at pressures >2 GPa. This dataset presents a compilation of global high-Sr TTG occurrences identified from published literature, and contains their compiled major and trace element and Nd isotope compositions.

GEOSCRAPE zircon database

This database contains a compilation of published zircon geochronology, chemistry and isotope data. The database was created through automated web scraping of the Figshare data repository. Data included U-Pb and Pb-Pb dating, Lu-Hf isotopes, trace element and rare earth element chemistry and isotopes. Where available, metadata on the analytical method, lithology, sample description and sampling coordinates are included. All analyses include a citation and doi link to the original data hosted on Figshare. See metadata table for descriptions of table headers. See associated manuscript for web scraping code.

Titanium stable isotope compositions of Neoarchean tonalite-trondhjemite-granodiorite (TTG) suites from the Eastern Goldfields Superterrane, Yilgarn Craton

We report the titanium (Ti) stable isotope compositions (δ49Ti) of Neoarchean (ca. 2700-2650 Ma) tonalite-trondhjemite-granodiorite (TTG) suites from the Eastern Goldfields Superterrane, Yilgarn Craton. Samples were selected to cover the full range of trace element compositions exhibited by TTGs, and are primarily from the Kalgoorlie-Kambalda region of the Kalgoorlie Terrane. Ti stable isotope compositions were measured using multicollector inductively coupled plasma mass spectrometry (MC-ICP-MS) at the Cardiff Earth Laboratory for Trace Element and Isotope Chemistry (CELTIC), Cardiff University. The Ti isotope compositions of these samples (file: 2025-009_Spencer-et-al_Ti-Isotope-Data.xlsx) are presented alongside a compilation of their major and trace element concentrations (file: 2025-009_Spencer-et-al_Compiled-Isotope-Major-Trace-Element-Data.xlsx) taken from the Western Australian Geochemistry Database (WACHEM). Most TTG samples have δ49Ti values between 0.2 to 0.6‰ that increase with SiO2 content, while two highly evolved TTGs have δ49Ti > 1‰. At SiO2 ≈ 70 wt% the different TTG geochemical groups display distinct Ti isotope compositions.

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