The broad objective of the research is to gain a fundamental understanding of the surface reaction chemistry of exhaust catalysts operating under cycling conditions. Using an integrated theoretical approach we specifically target NOx abatement, with particular emphasis on the appearance and destruction of surface oxide phases as the reactor conditions cycle from oxidative to reductive during the operation of the NOx Storage Reduction (NSR) catalyst system. Methodologically this requires material-specific, quantitative and explicitly time-dependent simulation tools that can follow the evolution of the system over the macroscopic time-scales of NSR cycles, while simultaneously accounting for the atomic-scale site heterogeneity and spatial distributions at the evolving surface. To meet these challenging demands we will develop a novel multi-scale methodology relying on a multi-lattice first-principles kinetic Monte Carlo (kMC) approach. As representative example the simulations will be carried out on a PdO(101)/Pd(100) surface oxide model, but care will be taken to ensure a generalization of the multi-lattice first-principles kMC approach to other systems in which phase transformations may occur and result in a change in the surface lattice structure depending upon environmental variables.
Irrigation in the Yanqi Basin, Sinkiang, China has led to water table rise and soil salination. A model is used to assess management options. These include more irrigation with groundwater, water saving irrigation techniques and others. The model relies on input data from remote sensing.The Yanqi Basin is located in the north-western Chinese province of Xinjiang.This agriculturally highly productive region is heavily irrigated with water drawn from the Kaidu River. The Kaidu River itself is mainly fed by snow and glacier melt from the Tian Mountain surrounding the basin. A very poor drainage system and an overexploitation of surface water have lead to a series of environmental problems: 1. Seepage water under irrigated fields has raised the groundwater table during the last years, causing strongly increased groundwater evaporation. The salt dissolved in the groundwater accumulates at the soil surface as the groundwater evaporates. This soil salinization leads to degradation of vegetation as well as to a loss of arable farmland. 2. The runoff from the Bostan Lake to the downstream Corridor is limited since large amount of water is used for irrigation in the Yanqi Basin. Nowadays, the runoff is maintained by pumping water from the lake to the river. The environmental and ecological system is facing a serious threat.In order to improve the situation in the Yanqi Basin, a jointly funded cooperation has been set up by the Institute of Environmental Engineering, Swiss Federal Institute of Technology (ETH) , China Institute of Geological and Environmental Monitoring (CIGEM) and Xinjiang Agricultural University. The situation could in principle be improved by using groundwater for irrigation, thus lowering the groundwater table and saving unproductive evaporation. However, this is associated with higher cost as groundwater has to be pumped. The major decision variable to steer the system into a desirable state is thus the ratio of irrigation water pumped from the aquifer and irrigation water drawn from the river. The basis to evaluate the ideal ratio between river and groundwater - applied to irrigation - will be a groundwater model combined with models describing the processes of the unsaturated zone. The project will focus on the following aspects of research: (...)
The natural capital of forests consists to a great extend of the forests environmental functions for human well-being, which not only include goods and services (source and sink functions) but also include life-support functions that reflect ecosystem performance (ecosystem functioning). Shifting the management approach from a traditional one to one that is more aware of the ecosystem complexity, the idea of 'ecosystem functioning is appearing to tackle gradual declines of ecosystem functions. Within CBDs framework, the Ecosystem Approach has been introduced on account of the necessity for open decision making with strong links between all stakeholders and the latest scientific knowledge due to uncertainty and unpredictability in nature. The Ecosystem Approach is still in need of further elaboration, even though as a concept Ecosystem Approach has been widely accepted. To aim forest enhancement, this approach has been regarded as the most feasible concept for the study area, the Bengawan Solo River Basin - Java, Indonesia. Therefore the principles and operational guidelines will be used to analyse and evaluate the current forest management in those areas of the Bengawan Solo River Basin, in which ecosystem function is the basis for forest development area. This research focuses on ecological functions of forests at various levels of ecosystem management planning, from the forestry sectors point of view.
The development of sustainable and efficient energy conversion processes at interfaces is at the center of the rapidly growing field of basic energy science. How successful this challenge can be addressed will ultimately depend on the acquired degree of molecular-level understanding. In this respect, the severe knowledge gap in electro- or photocatalytic conversions compared to corresponding thermal processes in heterogeneous catalysis is staggering. This discrepancy is most blatant in the present status of predictive-quality, viz. first-principles based modelling in the two fields, which largely owes to multifactorial methodological issues connected with the treatment of the electrochemical environment and the description of the surface redox chemistry driven by the photo-excited charges or external potentials.Successfully tackling these complexities will advance modelling methodology in (photo)electrocatalysis to a similar level as already established in heterogeneous catalysis, with an impact that likely even supersedes the one seen there in the last decade. A corresponding method development is the core objective of the present proposal, with particular emphasis on numerically efficient approaches that will ultimately allow to reach comprehensive microkinetic formulations. Synergistically combining the methodological expertise of the two participating groups we specifically aim to implement and advance implicit and mixed implicit/explicit solvation models, as well as QM/MM approaches to describe energy-related processes at solid-liquid interfaces. With the clear objective to develop general-purpose methodology we will illustrate their use with applications to hydrogen generation through water splitting. Disentangling the electro- resp. photocatalytic effect with respect to the corresponding dark reaction, this concerns both the hydrogen evolution reaction at metal electrodes like Pt and direct water splitting at oxide photocatalysts like TiO2. Through this we expect to arrive at a detailed mechanistic understanding that will culminate in the formulation of comprehensive microkinetic models of the light- or potential-driven redox process. Evaluating these models with kinetic Monte Carlo simulations will unambiguously identify the rate-determining and overpotential-creating steps and therewith provide the basis for a rational optimization of the overall process. As such our study will provide a key example of how systematic method development in computational approaches to basic energy sciences leads to breakthrough progress and serves both fundamental understanding and cutting-edge application.
Climate projections and trend analysis of historical data suggest that precipitation and temperature changes can dramatically alter the supply of and the demand for water in the human- and eco-systems. Moreover, anthropogenic landscape changes are occurring at unprecedented scales and rates given the societal needs for various (and often competing) ecosystem goods and services (food, energy, and water). How stable or resilient are the human- and eco- systems to climatic and anthropogenic perturbations remain a major societal concern. Of these concerns, hydrologic cycle changes, water resources availability and related management rank among the highest because of their importance in regulating human and ecological sustainability and climate feedbacks. A number of recent studies suggest that continental runoff increased throughout the 20th century despite a rapid increase in water consumption by humans and their activities. Scope of the project: The goal of this research program is on the overall impact of such changes on rainfall (the source of water) and concomitant replenishment of usable water supplies (e.g. ground- and stream- water) given their high priority to any future water resource planning. Even within this restricted scope, the barriers to scientific progress are numerous necessitating an inter-disciplinary approach that combines principles from eco-hydrology, hydraulics and fluid mechanics, soil physics, plant physiology, stochastic processes, dynamical systems theory, and water resources management. This project aims to build a network of researchers with complementary talents to begin progress on these fronts. Moreover, this network of researchers will be actively engaged in preparing the next generation of international scientists (via graduate student exchanges) who will be trained to approach such interdisciplinary societal problems and progress on them by adopting trans-disciplinary approaches now emerging from complex systems science.
Bacteria can trigger mineral formation by their metabolic activity or by provision of sorption and nucleation sites on cell surfaces. Sulfide minerals occur in marine and freshwater sediments primarily as the result of dissimilatory sulfate reduction which is mediated by a phylogenetically diverse group of Prokaryotes that gain their energy by anaerobic respiration with sulfate as terminal electron acceptor. In principle it is the reversal process of pyrite oxidation which generates acidic metal-rich waters causing severe environmental pollution in coal and metal ore mining areas. The formation of iron sulfides is a major process in controlling global element cycling, besides, it is the target process during the treatment of acid mine drainage by the use of dissimilatory sulfate reduction. The sustainability of bioremediation depends on the extent and stability of iron sulfides formed. However, so far little is known about iron sulfide formation under acidic conditions and the role that bacteria play in this process. The objectives of this project are i) to investigate the formation of iron sulfide minerals in sulfate-reducing enrichment cultures under low pH-conditions, ii) to analyse and characterise mineral structures and cell-mineral interactions, iii) to elucidate community structure and its response to varying pH values, and iv) to find out whether the involved bacteria benefit from iron sulfide precipitation. This study may contribute to our general understanding of biomineral formation and sulfate reduction under acidic conditions and may help us to further improve bioremediation strategies.
Wildtiere (Arten, Populationen, Individuen, Lebensräume, genetische Vielfalt) werden neben der Jagd von vielen anderen Landnutzungsaktivitäten beeinflusst, die sich im Wildlebensraum vielfach überlagern und oftmals miteinander konkurrieren. Insbesondere in Mehrfachnutzungs-Kulturlandschaften, wie dem Biosphärenpark Wienerwald, können die resultierenden Wechselwirkungen zwischen den Lebensraumansprüchen von Wildtieren, jagdlichen Nutzungsinteressen und anderen Landnutzungsansprüchen oftmals zu Konflikten führen, die der nachhaltigen Erhaltung heimischer Wildtierarten und ihrer Lebensräume, der Nachhaltigkeit der beteiligten Landnutzungen und einer nachhaltigen regionalen Entwicklung insgesamt abträglich sein können. Sektorale Nachhaltigkeitsansätze alleine sind unzureichend und können sogar unbeabsichtigte negative Auswirkungen auf andere Landnutzungen und auf das betreffende Ökosystem haben. Der nachhaltige Umgang mit Wildtieren kann letztlich nur gelingen, wenn alle im Wildlebensraum agierenden Nutzergruppen sich der Auswirkungen ihrer Tätigkeiten auf die Ressource 'Wildtier' sowie auf die jeweils anderen Nutzergruppen bewusst sind. Am Beispiel von 'Wildtieren und Jagd' wurden daher im Biosphärenpark Wienerwald modellhaft Konzepte, Inhalte und Instrumente für eine integrative, d. h. sektorübergreifend abgestimmte Nachhaltigkeitsbeurteilung mehrerer Landnutzergruppen entwickelt. Mittels angewandter und partizipativer Forschungsmethoden (Experteninterviews, breite Nutzerbefragungen, projektbegleitende Partizipation) wurden zentrale Schnittstellen (Antagonismen, Synergiepotenziale) zwischen Wildtieren, Jagd und weiteren regionalen Landnutzungen identifiziert, analysiert und bewertet. Als zentrales Ergebnis liegen sektorübergreifend abgestimmte Sets von Prinzipien, Kriterien und Indikatoren für ein integratives nachhaltiges Wildtiermanagement im Biosphärenpark Wienerwald vor. Die Bewertungssets dienen der Selbstbewertung wesentlicher regionaler Nutzergruppen (Forstwirtschaft, Landwirtschaft, Jagd, Freizeit- und Erholungsmanagement) und ermöglichen es diesen, jeweils eigene Einflussmöglichkeiten auf die nachhaltige Erhaltung von Wildtierarten, deren Lebensräumen und eine nachhaltige Jagd selbst zu überprüfen. Nachhaltigkeitsanforderungen anderer Nutzergruppen wurden dabei jeweils berücksichtigt. Somit wurde am Beispiel der stark vernetzten Thematik 'Umgang mit Wildtieren' erstmals der Schritt von der rein sektorbezogenen hin zu einer sektorübergreifend abgestimmten Erfassung der Nachhaltigkeit vollzogen. Weiters wurden Empfehlungen für ein integratives nachhaltiges Wildtiermanagement sowie für ein diesbezügliches Monitoring ausgearbeitet. Die Projektergebnisse sollen dazu beitragen, Wildtiere und deren Management möglichst konfliktfrei in eine nachhaltige Landnutzung im Biosphärenpark Wienerwald zu integrieren. Die Vollversion des Endberichtes samt Anhängen ist als Download-Publikation auf der Homepage der Österreichischen Akademie der Wissenschaften
Water repellency (WR) plays a significant role in a large number of soils all over the world. In many regions global warming will lead to drier land surfaces and thus, increasing the likeliness of actual water repellency for such soils. The hydrological effects of WR (surface runoff, water erosion, preferential flow) have been relatively well investigated in the last decades. However, its effect on the energy balance between soil and atmosphere has not been studied yet. We postulate that global warming does not only lead to an increase in WR of soils, but WR has an impact on the energy balance and thus, will lead to a feedback on global warming. In order to test our hypothesis, we want to determine all components of the energy- and water balance between soil and atmosphere for a strongly water repellent soil. As a reference we want to repeat the same measurements for the same soil, at which the WR has been suspended by application of a surfactants. While the laboratory studies aim to give insight into more principle processes, the lysimeter (bare and with plants) and field scale studies shall give information about integrated complex natural processes. The gained knowledge shall be implemented into a numerical simulation tool for modeling water and energy balances in order to predict the effects of WR under different atmospheric conditions and physical soil properties.
The mission of the TIDE project will be to enhance the broad transfer and take-up of 15 innovative urban transport and mobility concepts throughout Europe and to make a visible contribution to establish them as mainstream measures. The TIDE partners will make a range of new and feasible solutions easily accessible to address key challenges of urban transport such as energy efficiency, decarbonisation, demographic change, safety, access for all and new economic and financial conditions. TIDE will focus on 15 innovative concepts in five thematic clusters: financing models and pricing measures (1), non-motorised transport (2), network and traffic management to support traveller information (3), electric vehicles (4) and public transport organisation (5). Sustainable Urban Mobility Plans will be a horizontal topic to integrate the cluster activities. The project will provide a strong approach in methodology, content and outreach. The needs of practitioners in European cities and regions will be a guiding principle. A particular focus will also be on providing guidance for finding cost-efficient solutions (cost-benefit analysis). The project will refine existing and well proven transferability methodologies and integrate them into an easy to apply handbook. Face-to-Face training and exchange events as well as guidelines and e-learning on how to successfully implement innovative solutions will be the key tools to effectively support a wide range of take-up candidates in overcoming real or perceived barriers to implementation. A broad portfolio of dissemination activities will ensure a high visibility of the project. TIDE will actively support 15 committed cities in developing implementation scenarios. They will demonstrate how to successfully prepare implementation of innovative solutions and provide examples to a wider group of cities. An experienced and committed consortium will ensure that the advanced project approach will achieve a well visible impact.
The MSY concept was included as a principle in the 2009 Green Paper on the reform of the Common Fisheries Policy (CFP) in accordance with the global imperative to manage fish stocks according to the maximum sustainable yield (MSY). This implies a commitment to direct management of fish stocks towards achieving MSY by 2015. Attaining this goal is complicated by the lack of common agreement on the interpretation of 'sustainability' and 'yield' and by the effects that achieving MSY for one stock may have on other stocks and broader ecosystem, economic, or social aspects. MYFISH will provide definitions of MSY variants which maximize other measures of 'yield' than biomass and which account for the fact that single species rarely exist in isolation. Further, MYFISH will redefine the term 'sustainable' to signify that Good Environmental Status (MSFD) is achieved and economically and socially unacceptable situations are avoided, all with acceptable levels of risk. In short, MYFISH aims at integrating the MSY concept with the overarching principals of the CFP: the precautionary and the ecosystem approach. MYFISH will achieve this objective through addressing fisheries in all RAC areas and integrating stakeholders (the fishing industry, NGOs and managers) throughout the project. Existing ecosystem and fisheries models will be modified to perform maximization of stakeholder approved yield measures while ensuring acceptable impact levels on ecosystem, economic and social aspects. Implementation plans are proposed and social aspects addressed through active involvement of stakeholders. Finally, effects of changes in environment, economy and society on MSY variants are considered, aiming at procedures rendering the MSY approach robust to such changes. The expertise of 26 partners from relevant disciplines including fisheries, ecosystem, economic and social science are involved in all aspects of the project. Global experience is engaged from North America and the South Pacific.
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