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This dataset presents hydrogen sulfide (H2S) and nitrate (NO3-) concentrations in the water column at 15 stations in the Kiel Bight taken during the research cruises BE10/2018 (23.10.2018), BE03/2019 (15.03.2019), L23-13 (13.09.2023 - 15.09.2023), Hai24VE2 (24.09.2024) and EMB374 (04.09.2025 - 13.09.2025). Water samples were collected using Niskin bottles attached to a stainless-steel framework with CTD sensors. Concentrations of H2S and NO3- were measured photometrically (Hitachi U-2900). The data are used to describe seasonal hypoxia in the Kiel Bight water column and are combined with sediment and porewater data to identify controlling factors governing the accumulation of H2S at the seafloor. Furthermore, we compare the H2S measurements from the deepest Niskin bottle with bottom water H2S concentrations obtained from the benthic tracer profiler and from the overlying water in sediment cores. This allows us to illustrate H2S trends from several meters above the seafloor down to the sediment-water interface, and to discuss advantages and limitations of the different sampling techniques in characterizing geochemical conditions in the benthic environment.
This dataset presents porewater and bottom water data from 63 stations in the Kiel Bight taken during the research cruises BE03/2016 (08.03.2016), BE10/2016 (19.10.2016), BE10/2018 (23.10.2018), BE03/2019 (15.03.2019), L23-13 (13.09.2023 - 15.09.2023), Sagitta24-1 (16.09.2024), Sagitta24-2 (23.09.2024), L25-2b (09.02.2025 - 17.02.2025) and EMB374 (04.09.2025 - 13.09.2025). Short sediment cores (<50cm) were recovered using a Multicorer (MUC), Minicorer (MIC) or Rumohrlot (RL). At 22 of those stations, bottom water and porewater samples were analysed for total alkalinity (TA), ammonium (NH4+), sulfate (SO42-), hydrogen sulfide (H2S), dissolved iron (Fe2+) and dissolved manganese (Mn2+). At 41 stations, exclusively a bottom water sample was taken for H2S measurements. Bottom waters were sampled from the supernatant water in the sediment cores. Porewater samples were extracted from the sediments using rhizones. TA was determined by titration (METROHM 876 Dosimat Plus), NH4+ and H2S using a photometer (Hitachi U-2900), SO42- by Ion Chromatography (METROHM 761 Compact) and Fe2+ and Mn2+ by Inductively Coupled Plasma Optical Emission Spectroscopy (Varian 720-ES). The collected data will be used to determine the spatial and temporal variability of hydrogen sulfide in bottom waters of the Kiel Bight, (ii) identify the controlling factors governing the accumulation of hydrogen sulfide at the seafloor, and (iii) establish an early warning system of sulfidic seafloor conditions for regional stakeholders in the Baltic Sea.
The mixing ratio and bulk isotopic composition of nitrous oxide (N2O) was measured after wet extraction and purification of the air enclosed in 150 g ice core samples from EDC, EDML, Vostok, TALDICE, and NGRIP, following the analysis procedure described in Schmitt et al. (2014). The position-specific isotopic composition of N2O was measured after dry extraction and purification of the air enclosed in 600 g ice core samples from Vostok and Taylor Glacier, following the analysis procedure described in Menking et al. (2025). The mixing ratio and isotopic composition of in situ N2O – i.e., the fraction of N2O produced in the ice – was calculated using a mass balance approach (Soussaintjean et al., preprint). After gas extraction, the sample meltwater and ice chips were collected to measure the isotopic composition of nitrate (NO3-) following the bacterial denitrification method described in Erbland et al. (2013). Each sample was associated with its ice age and gas age based on the AICC2023 chronology (Bouchet et al., 2023) for EDC, EDML, Vostok, TALDICE, and NGRIP and Baggenstos et al. (2017, 2018) for Talyor Glacier. The samples cover the periods 11 – 26 ka, 41 – 75 ka, and 136 – 143 ka. Taylor Glacier is a horizontal core, meaning the age of the ice varies with distance along a transect close to the surface where the horizontal stratigraphy is preserved (Baggenstos et al., 2017).
The Global Ozone Monitoring Experiment-2 (GOME-2) instrument continues the long-term monitoring of atmospheric trace gas constituents started with GOME / ERS-2 and SCIAMACHY / Envisat. Currently, there are three GOME-2 instruments operating on board EUMETSAT's Meteorological Operational satellites MetOp-A, -B and -C, launched in October 2006, September 2012, and November 2018, respectively. GOME-2 can measure a range of atmospheric trace constituents, with the emphasis on global ozone distributions. Furthermore, cloud properties and intensities of ultraviolet radiation are retrieved. These data are crucial for monitoring the atmospheric composition and the detection of pollutants. DLR generates operational GOME-2 / MetOp level 2 products in the framework of EUMETSAT's Satellite Application Facility on Atmospheric Chemistry Monitoring (AC-SAF). GOME-2 near-real-time products are available already two hours after sensing. The operational H2O total column products are generated using the algorithm GDP (GOME Data Processor) version 4.x integrated into the UPAS (Universal Processor for UV/VIS Atmospheric Spectrometers) processor for generating level 2 trace gas and cloud products. The total H2O column is retrieved from GOME solar backscattered measurements in the red wavelength region (614-683.2 nm), using the Differential Optical Absorption Spectroscopy (DOAS) method. For more details please refer to relevant peer-review papers listed on the GOME and GOME-2 documentation pages: https://atmos.eoc.dlr.de/app/docs/
During the research cruises BE03/2016 (08.03.2016), BE10/2016 (19.10.2016), BE10/2018 (23.10.2018), BE03/2019 (15.03.2019), L23-13 (13.09.2023 - 15.09.2023), Sagitta24-1 (16.09.2024), Sagitta24-2 (23.09.2024), Hai24VE2 (24.09.2024), L25-2b (09.02.2025 - 17.02.2025) and EMB374 (04.09.2025 - 13.09.2025), CTDs were deployed and sediment corers were retrieved at 99 stations in Kiel Bight in the southwestern Baltic Sea. Water column oxygen concentrations were determined using oxygen sensors attached to the CTD framework. At selected water depths, water samples were collected with Niskin bottles for the analysis of nitrate concentrations using an autoanalyzer. Short sediment cores (<50cm) were recovered using a Multicorer (MUC), Minicorer (MIC) or Rumohrlot (RL). Bottom waters were sampled from the supernatant water in the sediment cores. Solid phase sediment samples were analyzed for total organic carbon using an element analyzer. Porewater was extracted from the sediment cores using rhizones and analyzed for total alkalinity (titration), ammonium (photometer), sulfate (ion chromatography), hydrogen sulfide (photometer), dissolved iron (ICP-OES) and dissolved manganese (ICP-OES). The collected data will be used to (i) determine the spatial and temporal variability of hydrogen sulfide in bottom waters of the Kiel Bight, (ii) identify the controlling factors governing the accumulation of hydrogen sulfide at the seafloor, and (iii) establish an early warning system of sulfidic seafloor conditions for regional stakeholders in the Baltic Sea.
The Sternfahrt-10 of the MOSES campaign, from 29th August until the 15th of September 2023, had two objectives. One was to follow the dispersion of pollutants transported by the Elbe water into the North Sea, previously observed during the Elbe-Freshwater and Elbe-Tidal cruises. And second the distribution of the Elbe water within the German Bight. Therefore, drifter groups were deployed to follow individual water parcels. Those drifters were followed subsequently by three ships (RV Ludwig Prandtl, RV Littorina, RV Mya II), to extend the time period of measurements. Along the tracks, water samples were taken close to the drifters, alternatively at stations from previous cruises, resulting in 12 to 24 sampling points per week. In terms to detect the concentration of a variety of nutrients and carbon compounds from the south-eastern North Sea up to the island Amrum. Additionally, basic hydrographic parameters and greenhouse gases were sampled continuously throughout the whole cruise. Those results are not part of the present dataset, but can be found here, https://doi.org/10.1594/PANGAEA.971874. To ensure the comparability of the measured parameters a transportable container laboratory was passed from ship to ship always equipped with the same sensor systems. Just for specific water samples some special equipment was added. A map of the different tracks as well as information about the used sensors and data treatment, you can find in the additional material. For more detailed information about the MOSES Project and the cruise Sternfahrt-10, see the article cited in references.
Teil der Statistik "Treibhausgasemissionen" Raum: Bayern
Das Ziel dieses Verbundvorhabens ist die quantitative Bestimmung der Minderung von Nitrateinträgen in das Grundwasser durch den Abbau von Nitrat zu N2O und N2 durch Denitrifikation in der Drainzone. Dazu wird die Denitrifikation in Proben aus der Drainzone in Abhängigkeit wichtiger Bodeneigenschaften gemessen und ein Modell entwickelt und parametrisiert. Dazu werden typische Standorte in Deutschland mit unterschiedlich mächtigen Drainzonen untersucht. Die modellhafte Beschreibung wird auch eine standortspezifische Bewertung des Nitratabbaus ermöglichen. Damit wird das Verbundvorhaben unsere Kenntnisse über den Nitratabbau und die N2O und N2 Produktion im Unterboden, speziell aus der Drainzone erweitern und damit die Grundlage zu einem Landmanagement legen, das die Umsätze von Nitrat in dieser Zone berücksichtigt.
Im Rahmen eines früheren ReFoPlan-Projekts (FKZ 3717 62 205, Mobile Messsysteme für Innenraumschadstoffprobleme) wurde ein neues, zeitlich hochauflösendes Messsystem zur Erfassung einer Vielzahl von Klima- und Schadstoffparametern im Innenraum konstruiert. (Die Parameter umfassen Temperatur, relative Luftfeuchte, Luftdruck, Flüchtige organische Verbindungen (VOC), Gammastrahlung, Radon, die Beleuchtungsstärke, CO, H2S, NO, NO2, O3, SO2, CO2, PM1, PM2,5 und PM10). Von diesem Gerät soll eine Kleinserie gebaut und diese im Rahmen einer Feldkampagne im Realeinsatz bei Probanden getestet werden. Ziel ist es, die Voraussetzungen zu schaffen, dass dieses Gerät bei künftigen Bevölkerungsstudien (z.B. GerES) eingesetzt und somit neue innovative Parameter zur Qualität des Wohnumfeldes der Probanden erfasst werden können.
Die thermische Behandlung des stickstoffreichen Abfallstoffs Klärschlamm erfolgt überwiegend in stationären Wirbelschichten. Die Betriebsführung dieser Anlagen fokussiert auf eine weitgehende Minderung der Stickoxidemissionen und berücksichtigt bisher nur teilweise die Minderung des klimarelevanten Abgasparameters Lachgas (N2O). Die Treibhausgaswirkung von N2O ist um den Faktor 300 höher im Vergleich zu CO2 und kann bei hohen Emissionen die Klimabilanz der Klärschlammverbrennung deutlich verschlechtern. Infolge der Umsetzung der Vorgaben der AbfKlärV wird zu den bestehenden Anlagen ein massiver Zubau an neuen Monoverbrennungsanlagen ( 30) erwartet, welcher bis 2029 weitgehend abgeschlossen sein soll. In diesem Zusammenhang bietet sich durch Anwendung geeigneter Feuerungs- und Abgasreinigungskonzepte die Möglichkeit, die Klimawirkung der thermischen Klärschlammbehandlung insgesamt zu mindern. Im Rahmen des Vorhabens sollen Emissionsdaten von NOx/N2O unter Berücksichtigung der angewandten Feuerungs- und Abgasreinigungskonzepte ermittelt und ausgewertet werden. Basierend hierauf werden Einsatzbereiche und Minderungseffizienzen primärer und sekundärer Schadgasminderungsmaßnahmen identifiziert und praktische Handlungsempfehlungen zur Minderung der NOx/N2O-Emissionen abgeleitet.
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