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B 2.3: Transport of agrochemicals in a watershed in Northern Thailand - Phase 3

Das Projekt "B 2.3: Transport of agrochemicals in a watershed in Northern Thailand - Phase 3" wird vom Umweltbundesamt gefördert und von Universität Hohenheim, Institut für Bodenkunde und Standortslehre, Fachgebiet Biogeophysik durchgeführt. Land use changes of the last decades in the mountainous regions of Northern Thailand have been accompanied by an increased input of agrochemicals, which might be transferred to rivers by surface and/or subsurface flow. Where the river water is used for household consumption, irrigation and other purposes, agrochemical losses pose a serious risk to the environment and food safety. In the first and the second phase, subproject B2 collected data on and gained knowledge of the vertical and lateral transport processes that govern the environmental fate of selected agrochemicals at the plot and the hillslope scale (Ciglasch et al., 2005; Kahl et al., 2006). In the third phase, B2.3 will turn from the hillslope to the watershed scale. For simulation of water flow and pesticide transport the SWAT model (Neitsch et al., 2002b) will be adapted and used. The study area will be the Mae Sa watershed (138 km2), which includes the Mae Sa Noi subcatchment where B2 carried out detailed investigations during the last two phases. The specific focus of the subproject will be the parameterization and calibration of the SWAT model and its integration into the model network of the SFB. The SFB database has been established and can be used for model parameterization. In addition, high-quality geo-data are available from the Geoinformatic and Space Technology Development Agency (GISTDA) in Chiang Mai. For model calibration, discharge measurements are available for the Mae Sa Noi subcatchment (12 km2) and for the neighboring Mae Nai subcatchment (18 km2). To collect data on the Mae Sa watershed discharge, at the very beginning of the third phase gauging stations will be established in a midstream position and at the outlet of the watershed. Pesticide fluxes will be measured at each gauging station as well as in the Mae Sa Noi subcatchment, where B2.2 has operated two flumes equipped with automatic discharge-proportional water samplers since 2004. Rainfall distribution and intensity will be monitored with a net of automatic rain gauges. Hydrograph separation will be performed using soil and river temperatures (Kobayashi et al., 1999). Within the watershed temperature loggers will be installed at different soil depths to measure the temperature of the different discharge components. Already at the beginning of the second year of the third phase we will start to couple the SWAT model with land use and farm household models of the SFB and to use the model to assess the effect of land use and land management changes on the loss of pesticides to surface waters.

B 2: Lateral water flow and transport of agrochemicals - Phase 1

Das Projekt "B 2: Lateral water flow and transport of agrochemicals - Phase 1" wird vom Umweltbundesamt gefördert und von Universität Hohenheim, Institut für Bodenkunde und Standortslehre durchgeführt. The project aims at developing a model of the dynamics of agrochemicals (fertilisers, pesticides) and selected heavy metals on a regional scale as a function of cropping intensity in the highland areas of Northern Thailand. The model shall predict the effects of cropping intensity on mobility and leaching of agrochemicals in the agriculturally used system itself but also on the chemical status of neighbouring ecosystems including downstream areas. The methods for measuring and estimating the fluxes of agrochemicals in soils will be adapted to the conditions of the soils and sites in Northern Thailand. Fluxes of agrochemicals will be measured in fruit tree orchards on the experimental sites established together with projects B1, C1 and D1. Also, processes governing the dynamics of agrochemicals will be studied. The objectives for the first phase are as follows: - To identify suitable study sites - To establish the methods for measuring the fluxes of agrochemicals in the study sites - To adopt the analytical procedures for pesticides - To identify and parametrise the processes governing the mobility of agrochemicals - To identify the major chemical transformation processes for agrochemicals in the soils of the project area - To establish models of the fate of agrochemicals an the plot scale. Dynamics of agrochemicals include processes of mobilisation/immobilisation, degradation and transport. Both, experiments and field inventories are needed to elucidate the complex interaction of the various processes. Field measurements of the fluxes of nutrient elements (N, P, K, Ca, Mg, Mn, Zn, Cu), pesticides and some heavy metals will be conducted at different regional scales (plot, agricultural system, small catchment, region). Laboratory and field experiments consider chemical, physicochemical and biological processes. Biological processes and degradation of pesticides will not be considered in the first phase of the project, however, they should be included later on. The project as a whole is broken down into three essential parts, which consecutively follow each other. The subproject is methods- and processes-orientated. Methods, which were developed in Hohenheim to quantify the fluxes of chemicals in soils have to be adapted to meet the requirements of the specific conditions in the study area. Recently, these methods are already under development in tropical environments (Vietnam, Costa Rica). After adaptation the methods will be used to yield flux data on the plot scale. These data are needed to help deciding which of the hypothesised processes are of major importance for modelling the dynamics of agrochemicals. The final outcome of this project phase are models of the fate of agrochemicals as a function of management intensity on the plot scale.

Tools for Sustainabiltity Impact Assessment of the Forestry- Wood Chain

Das Projekt "Tools for Sustainabiltity Impact Assessment of the Forestry- Wood Chain" wird vom Umweltbundesamt gefördert und von Universität Hamburg, Department für Biologie, Zentrum Holzwirtschaft des Johann Heinrich von Thünen-Institut, Bundesforschungsinstitut für Ländliche Räume, Wald und Fischerei durchgeführt. The objective of EFORWOOD is to develop a quantitative decision support tool for Sustainability Impact Assessment of the European Forestry-Wood Chain (FWC) and subsets thereof (e.g. regional), covering forestry, industrial manufacturing, consumption and recycling. The objective will be achieved by:a) defining economic, environmental and social sustainability indicators ,b) developing a tool for Sustainability Impact Assessment by integrating a set of models ,c) supplying the tool with real data, aggregated as needed and appropriate,d) testing the tool in a stepwise procedure allowing adjustments to be made according to the experiences gained,e) applying the tool to assess the sustainability of the present European FWC (and subsets thereof) as well the impacts of potential major changes based on scenarios,f) making the adapted versions of the tool available to stakeholder groupings (industrial, political and others).The multi-functionality of the FWC is taken into account by using indicators to assess the sustainability of production processes and by including in the analysis the various products and services of the FWC. Wide stakeholder consultations will be used throughout the process to reach the objective. EFORWOOD will contribute to EU policies connected to the FWC, especially to the Sustainable Development Strategy. It will provide policy-makers, forest owners, the related industries and other stakeholders with a tool to strengthen the forest-based sector's contribution towards a more sustainable Europe, thereby also improving its competitiveness. To achieve this, EFORWOOD gathers a consortium of highest-class experts, including the most representative forest-based sector confederations.EFORWOOD addresses with a high degree of relevance the objectives set out in the 3rd call for proposals addressing Thematic Sub-priority 1.1.6.3 Global Change and Ecosystems, topic V.2.1. Forestry/wood chain for Sustainable Development. Prime Contractor: Stiftelsen Skogsbrukets Forskningsinstitut, Skogforsk; Uppsala; Sweden.

Biomass fluidised bed gasification with in situ hot gas cleaning (AER-GAS II)

Das Projekt "Biomass fluidised bed gasification with in situ hot gas cleaning (AER-GAS II)" wird vom Umweltbundesamt gefördert und von Zentrum für Sonnenenergie- und Wasserstoff-Forschung Baden-Württemberg durchgeführt. Objective: The project aim is a low-cost gasification process with integrated in-situ gas cleaning for the conversion of biomass into a product gas with high hydrogen concentration, high heating value and low tar/alkali/sulphur concentration in one process step for s ubsequent power production. The proposed process uses in-situ CO2 capture (AER, Absorption Enhanced Reforming). It is more efficient than conventional gasification due to (i) the in-situ integration of the reaction heat of CO2 absorption and water-gas shif t reaction heat (both exothermic) into the gasification and (ii) the internal reforming of primary and secondary tars, which cuts off the formation of higher tars. Thus, the chemical energy of tars remains in the product gas. The product gas after dust rem oval can directly be used in a gas engine for electricity generation. Due to the low operation temperature (up to 700 C) and due to CaO-containing bed materials, the proposed process allows the use of problematic feedstocks such as biomass with high minera l and high moisture content, e.g. straw, sewage sludge, etc., leading to an increased market potential for biomass gasification processes. Screening/development of absorbent materials with high attrition stability and tar cracking properties will be carrie d out. Analysis of tar formation/decomposition process will be studied in a lab-scale fixed bed reactor and a 100 kWth circulating fluidised bed reactor (continuous mode). With the acquired data, the 8 MWth biomass plant at Guessing, Austria, will be opera ted with absorbent bed material in order to prove the feasibility of a scale-up and to assess the economical aspects of the process. In order to point out the market potential, the cost reduction of the AER technology will be quantified in comparison with the conventional gasification power plant. Expected results will be: (i) a broad knowledge of the proposed process and (ii) a low-cost technology for biomass gasification with subsequent power production.

SIRRO: Siberian River Run-Off

Das Projekt "SIRRO: Siberian River Run-Off" wird vom Umweltbundesamt gefördert und von Universität Hamburg, Zentrum für Meeres- und Klimaforschung, Institut für Meereskunde (IfM) durchgeführt. SIRRO is a bilateral German-Russian project funded by the BMBF and russian authorities. The project investigates the nature and the impact of Siberian river runoff from Ob and Yenisei into the Kara Sea. In SIRRO, the Institute for Oceanography, Hamburg, is responsible for the high-resolution circulation modelling of the Ob and Yenisei estuaries and surrounding areas of the Kara Sea. The simulated flow fields will be used for transport and dispersion modelling of dissolved and particulate bio-geochemical tracers such as dO18, C13, nutrients, suspended matter or DOC.

Impact of transgenic crops on fertility of soils with different management history

Das Projekt "Impact of transgenic crops on fertility of soils with different management history" wird vom Umweltbundesamt gefördert und von Forschungsinstitut für biologischen Landbau Deutschland e.V. durchgeführt. What impact does transgenic maize have on soil fertility? Among the factors that determine soil fertility is the diversity of the bacteria living in it. This is in turn affected by the form of agriculture practiced on the land. What role do transgenic plants play in this interaction? Background Soil fertility is the product of the interactions between the parental geological material from which the soil originated, the climate and colonization by soil organisms. Soil organisms and their diversity play a major role in soil fertility, and these factors can be affected by the way the soil is managed. The type of farming, i.e. how fertilizers and pesticides are used, has a major impact on the fertility of the soil. It is known that the complex interaction of bacterial diversity and other soil properties regulates the efficacy of plant resistance. But little is known about how transgenic plants affect soil fertility. Objectives The project will investigate selected soil processes as indicators for how transgenic maize may possibly alter soil fertility. The intention is in particular to establish whether the soil is better able to cope with such effects if it contains a great diversity of soil bacteria. Methods Transgenic maize will be planted in climate chambers containing soils managed in different ways. The soil needed for these trials originates from open field trials that have been used for decades to compare various forms of organic and conventional farming. These soils differ, for example, in the way they have been treated with pesticides and fertilizers and thus also with respect to their diversity of bacteria. The trial with transgenic maize will measure various parameters: the number of soil bacteria and the diversity of their species, the quantity of a small number of selected nutrients and the decomposition of harvest residues. It will be possible to conclude from this work how transgenic plants affect soil fertility. Significance The project will create an important basis for developing risk assessments that incorporate the effects of transgenic plants on soil fertility.

Biopores in the subsoil: Formation, nutrient turnover and effects on crops with distinct rooting systems (BioFoNT)

Das Projekt "Biopores in the subsoil: Formation, nutrient turnover and effects on crops with distinct rooting systems (BioFoNT)" wird vom Umweltbundesamt gefördert und von Universität Bonn, Institut für Organischen Landbau durchgeführt. Perennial fodder cropping potentially increases subsoil biopore density by formation of extensive root systems and temporary soil rest. We will quantify root length density, earthworm abundance and biopore size classes after Medicago sativa, Cichorium intybus and Festuca arundinacea grown for 1, 2 and 3 years respectively in the applied research unit's Central Field Trial (CeFiT) which is established and maintained by our working group. Shoot parameters including transpiration, gas exchange and chlorophyll fluorescence will frequently be recorded. Precrop effects on oilseed rape and cereals will be quantified with regard to crop yield, nutrient transfer and H2-release. The soil associated with biopores (i.e. the driloshpere) is generally rich in nutrients as compared to the bulk soil and is therefore supposed to be a potential hot spot for nutrient acquisition. However, contact areas between roots and the pore wall have been reported to be low. It is still unclear to which extent the nutrients present in the drilosphere are used and which potential relevance subsoil biopores may have for the nutrient supply of crops. We will use a flexible videoscope to determine the root-soil contact in biopores. Nitrogen input into the drilosphere by earthworms and potential re-uptake of nitrogen from the drilosphere by subsequent crops with different rooting systems (oilseed rape vs. cereals) will be quantified using 15N as a tracer.

AURORa - Investigation of the Radar Backscatter of Rain Impinging on the Ocean Surface

Das Projekt "AURORa - Investigation of the Radar Backscatter of Rain Impinging on the Ocean Surface" wird vom Umweltbundesamt gefördert und von Universität Hamburg, Zentrum für Meeres- und Klimaforschung, Institut für Meereskunde (IfM) durchgeführt. Over land, observations of rain rates are more or less operational. To obtain information about precipitation at the coastal zones, weather radars are used. However, over the oceans, especially away from the main shipping routes, no direct precipitation measurements are performed. In these regions, satellite data can provide information about precipitation events. Satellites deploying passive and active microwave sensors can operate independently of cloud cover and time of day. Passive microwave sensors give crude estimates of rain rates over large areas but cannot resolve small-scale rain events of short duration as are often observed in the tropics, for example. Active microwave sensors with high resolutions, such as synthetic aperture radars can provide more reliable information. Though the effect of rain on the atmosphere is a very topical area of research, the radar backscattering mechanisms at the water surface during rain events combined with wind are still not well understood. The purpose of this project is to investigate the radar backscattering from the water surface in the presence of rain and wind in order to interpret satellite radar data produced by active microwave sensors. Furthermore, the results should be embedded into models of the radar backscattering from the water surface to allow for estimating rain rates by using satellite data. Research topics: Rain impinging on a water surfaces generates splash products including crowns, cavities, stalks and secondary drops, which do not propagate, and ring waves and subsurface turbulence. We are investigating this phenomena at the wind-wave tank of the University of Hamburg. The tank is fitted with an artificial rain simulator of 2.3 m2 area mounted 4.5 m over the water surface. Rain drops of 2.1 and 2.9 mm in diameter with rain rates up to 100 mm/h have been produced. Wind with speeds 10 m/s and monomolecular slicks act on the water surface. The influence of the rain on the water surface is measured with a resistance type wire gauge, a two dimensional laser slope gauge and an coherent 9.8 GHz (x band) continuous wave scatterometer operating at VV-, HH- and HV-polarization. The influence of rain below the water surface is measured with colored raindrops which are observed with a video camera to investigate the turbulent motion and the depth of the mixed layer. At the North Sea Port of Buesum in Germany, a scatterometer operating at all polarizations and five frequencies will be mounted during summer of this year. The radar backscatter of the sea surface during rain events will be measured in combination with meteorological observations. With help of these measurements, existing radar backscatter models of the water surface will be improved for the presence of rain events. To validate the improved models, ERS-2 SAR-images will be compared with weather radar data.

Storage of hydrogen in hydrides

Das Projekt "Storage of hydrogen in hydrides" wird vom Umweltbundesamt gefördert und von Weierstraß-Institut für Angewandte Analysis und Stochastik durchgeführt. Hydrogen is the ideal synthetic fuel to convert chemical energy into electrical energy or into motive power because it is light weight, highly abundant and its oxidation product is vapor of water. Thus its usage helps to reduce the greenhouse gases and it conserves fossile resources. There is even a clean way to produce hydrogen by electrolysis of water by means of photo voltaics (SvW06, VSM05, PMM05). There are various possibilities to store the hydrogen for later use: Liquid and gaseous hydrogen can be stored in a pressure vessel, hydrogen can be adsorped on large surface areas of solids, and finally crystal lattices of metals or other compounds can be used as the storage system, where hydrogen is dissolved either on interstitial or on regular lattice sites by substitution (SvW06, San99). The latter process and its reversal is called hydriding respectively dehydriding. The subject of this proposal is the modeling and simulation of that process. The main problem of a rechargeable lithium-ion battery is likewise a storage problem, because in a rechargeable battery, both the anode and cathode do not directly take part in the electrochemical process that converts chemical energy into electrical energy, rather they act as host systems for the electron spending element, which is here lithium (Li). During the last month the applicant developed and exploited a mathematical model that is capable to capture the storage problem of an iron phosphate (FePO4) cathode, where the Li atoms are stored on interstitial lattice sites (DGJ07).

Remote sensing of aerosols, clouds and trace gases using synergy of AATSR, MERIS, and SCIAMACHY onboard ENVISAT

Das Projekt "Remote sensing of aerosols, clouds and trace gases using synergy of AATSR, MERIS, and SCIAMACHY onboard ENVISAT" wird vom Umweltbundesamt gefördert und von Universität Bremen, Institut für Umweltphysik durchgeführt. Accurate satellite retrieval algorithms are needed to study long-term trends in trace gas abundances related to climate change. The main aim of this project is to develop improved aerosol and cloud retrieval algorithms in order to get more accurate SCIAMACHY trace gas retrievals. The results will contribute to a better understanding of aerosol and cloud properties and their changes on a global scale. This will be achieved by utilising the synergetic data from the optical instruments onboard ENVIronmental SATellite (ENVISAT), launched by the European Space Agency (ESA) on March 1st, 2002. The data of Advanced Along-Track Scanning Radiometer (AATSR), Medium Resolution Imaging Spectrometer (MERIS), and SCIAMACHY, all of which measure the same ground scene, will be used. The three instruments continue to have excellent performance and have already generated more than five years of data. Compared to just one single instrument, combined data from these optical instruments having different spatial resolutions, observation modes, spectral resolutions and spectral bands characterize aerosol, cloud, and trace gas properties to a much better degree. In this project, a new validation and testing strategy based on extended realistic simulated satellite scenes will be followed.

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