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The autonomous surface vehicle HALOBATES collected key climate variables, including sea surface temperature (SST) and salinity (SSS), during the RV Heincke cruise HE626 in the German Bight. HALOBATES recorded SST and SSS at seven different depths with a high vertical resolution of approximately 10 cm, ranging from the near-surface layer (NSL) (between 30 and 100 cm) to the sea-surface microlayer (SML) (uppermost millimeter). Temperature and conductivity (used for salinity calculation) were measured using conductivity, temperature, and depth (CTD) sensors connected to a flow-through system on HALOBATES. Additional temperature sensors were placed beneath the catamaran to capture in-situ temperature at six depths within the NSL. Salinity measurements were adjusted using discrete water samples to correct for any sensor biases. During the operation, two data loggers equipped with meteorological stations on the catamaran monitored essential weather conditions. HALOBATES was in operation from July 21, 2023, to August 8, 2023.
The autonomous surface vehicle HALOBATES measured Essential Climate Variables (ECV), such as sea surface temperature (SST) and salinity (SSS), during the RV Heincke cruise HE614 in the German Bight. HALOBATES captured the SST and SSS at seven depths with a high vertical resolution of about 10 cm, from the near-surface layer (NSL) (between 30 and 100 cm) and the sea surface microlayer (SML) (upper millimeter). Conductivity, temperature, and depth (CTD) sensors measured temperature and conductivity (for salinity calculation) via a flow-through system on HALOBATES. Additional temperature sensors were mounted underneath the catamaran to measure in-situ temperature in situ at six depths in the NSL. Salinity was corrected with discrete water samples to remove biases between the sensors. Two data loggers with several meteorological stations on the catamaran captured important weather variables during operation time. The surfactant concentration was measured from discrete samples of SML and 100 cm depth. HALOBATES was operated between 01 March 2023 and 22 March 2023.
We studied dissolved organic matter (DOM) dynamics in the sea surface microlayer (SML) during a multidisciplinary mesocosm study at the Sea sURface Facility (SURF) of the Institute for Chemistry and Biology of the Marine Environment (ICBM) in Wilhelmshaven, Germany (53.5148 °N, 8.1463 °E). The study was conducted from 18 May to 16 June 2023 as part of the BASS research unit (Biogeochemical processes and Air-sea exchange in the Sea-Surface microlayer). This dataset contains environmental data, including dissolved organic carbon (DOC), dissolved organic nitrogen (DON) and DOM molecular indices (MLBwL, Ibio, Iphoto, IDEG) calculated from ultrahigh-resolution mass spectrometry data (Fourier-transform ion cyclotron resonance mass spectrometer, FT-ICR-MS). Furthermore, we present attenuated total reflectance Fourier Transform Infrared (ATR-FTIR) data from representative samples for each bloom phase. General metadata from the multidisciplinary mesocosm study, including temperature, salinity and chlorophyll a, are provided in Bibi et al. on PANGAEA at the following link: doi:10.1594/PANGAEA.984101.
We studied dissolved organic matter (DOM) dynamics in the sea surface microlayer (SML) during a mesocosm study at the Sea sURface Facility (SURF) of the Institute for Chemistry and Biology of the Marine Environment (ICBM) in Wilhelmshaven, Germany (53.5148 °N, 8.1463 °E). The study was conducted from 18 May to 16 June 2023 as part of the multidisciplinary BASS research unit (Biogeochemical processes and Air-sea exchange in the Sea-Surface microlayer). SURF was filled with pretreated natural seawater from the nearby Jade Bay (53° 28' 42'' N, 8° 12' 15'' E) to replicate natural conditions. We selected this approach to examine the regrowth of surviving phytoplankton cells after the initial water treatments, simulating a native microbial community starting with almost no bioproduction or pre-existing bioproduction products. To induce and maintain the phytoplankton bloom, inorganic nitrogen, phosphorus, and silicate were added on May 26, May 31, and June 01, 2023. By that, we induced an algal bloom of Emiliania huxleyi and Cylindrotheca closterium. Water samples were collected using a glass plate for the SML and a tube at 40 cm depth for the underlying water (ULW). This dataset contains DOM molecular data from ultrahigh-resolution mass spectrometry (Fourier-transform ion cyclotron resonance mass spectrometer, FT-ICR-MS), molecular indices calculated from FT-ICR-MS data (Ibio, Iphoto, IDEG) and environmental data, including dissolved organic carbon (DOC) and dissolved organic nitrogen (DON). Furthermore, it contains attenuated total reflectance Fourier Transform Infrared (ATR-FTIR) data from representative samples for each bloom phase. By combining molecular analyses with nutrient and bloom-phase data, we highlight the in situ production of carbohydrate-like and laminarin-derived DOM as a significant contributor to SML composition. General metadata from the multidisciplinary mesocosm study, including temperature, salinity and chlorophyll a, are provided in Bibi et al. on PANGAEA at the following link: doi:10.1594/PANGAEA.984101.
The autonomous surface vehicle HALOBATES measured Essential Climate Variables (ECV), such as sea surface temperature (SST) and salinity (SSS), during the RV Heincke cruise HE609 in the German Bight. HALOBATES captured the SST and SSS at seven depths with a high vertical resolution of about 10 cm, from the near-surface layer (NSL) (between 30 and 100 cm) and the sea surface microlayer (SML) (upper millimeter). Conductivity, temperature, and depth (CTD) sensors measured temperature and conductivity (for salinity calculation) via a flow-through system on HALOBATES. Additional temperature sensors were mounted on the catamaran to contact the water at six depths in the NSL directly. Salinity was corrected with discrete samples, and biases between the sensors were removed. Two data loggers with several weather stations on HALOBATES captured important weather variables during operation time. HALOBATES was operated between 05 October 2022 and 23 October 2022.
This dataset contains daily averaged physical and chemical parameters measured during a mesocosm experiment conducted at Sea Surface Facility (SUR) in Wilhelmshaven, Germany (53.5148° N, 8.1461° E) in 2023. Parameters include daily average air temperature, Daily Average Incoming Solar Irradiance, Daily Average Reflected Solar Irradiance, and Daily Average Albedo derived from in situ measurements. The dataset provides an overview of environmental conditions throughout the experiment, supporting the interpretation of biogeochemical and ecological processes described in the related publication Bibi et al., 2025.
This collection (bundled publication) includes datasets from a mesocosm experiment conducted in spring 2023 at the Sea Surface Facility (SURF), Wilhelmshaven, Germany (53.5148° N, 8.1461° E). The experiment initiated a phytoplankton bloom under controlled conditions to examine surface ocean biogeochemistry and sea-surface microlayer (SML) processes. Daily samples were collected from the SML and underlying water (40 cm depth) and analyzed for physical, chemical, and biological parameters. Measurements include meteorological conditions (air temperature, solar irradiance, and albedo), surfactants, nutrients, pigments, particulate and dissolved organic carbon and nitrogen, and additional biogeochemical variables. These datasets provide environmental and biogeochemical context supporting studies on surface ocean processes and are described in detail in the related publication Bibi et al. (2025).
The file contains data from the Marine Carbon System. It gathered parameters from the inorganic carbon and incorporate the organic alkalinity as a main contributor to the sea surface microlayer (SML) compared to the Underlaying Water (ULW). Data was collected during Mesocosm Study from 18-May to 17-July 2024 in the Sea sURface Facility (SURF), Institute for Chemistry and Biology of the Marine Environment, Wilhelmshaven, Germany. Discrete samples to measure Dissolved Inorganic Carbon (DIC), Total Alkalinity (TA) and Organic Alkalinity (OA) were collected. For SML data, DIC, TA and OA was collected every third day following the glass‑plate technique (Harvey and Burzell, 1972). The ULW data, DIC, TA and OA were collected every day using a suction system to collect the sample from 0.4 m depth. Discrete samples were transported to the laboratory for further analysis; DIC was determined coulometrically (CM5017, UIC, IL, USA), and TA concentration was directly measured by high-precision closed-cell potentiometric titration (916 Ti-Touch, Metrohm, Switzerland). OA concentration was determined directly after TA was measured, using the same sample (from which all carbonate species had been purged), denoted as back titration. The dataset includes quality flags 0-4 with flags 1 and 2 are ready for use. See metadata for more information.
Here we present the dissolved organic matter (DOM) data of the sea surface microlayer (SML) and underlying water (ULW) during a multidisciplinary mesocosm study at the Sea sURface Facility (SURF) of the Institute for Chemistry and Biology of the Marine Environment (ICBM) in Wilhelmshaven, Germany (53.5148 °N, 8.1463 °E). The study was conducted from 18 May to 16 June 2023. Water samples were collected using a glass plate for the SML and a tube at a depth of 40 cm. DOM was extracted and desalinated by solid-phase extraction as described by Dittmar et al. (2008). The extracts were stored frozen in methanol until analysis. Aliquots were mixed with 50% ultrapure water (50:50 v/v) and diluted to a final carbon concentration of 2.5 ppm. DOM composition was analysed using a SolariX XR FT-ICR-MS (Bruker Daltonik GmbH, Bremen, Germany) with a 15 Tesla superconducting magnet and an electrospray ionisation source (ESI; Bruker Apollo II ion source) in negative ion mode. Data processing and molecular formula assignment were performed in ICBM-OCEAN, as described by Merder et al. (2020).
The effects of a phytoplankton bloom and photobleaching on colored dissolved organic matter (CDOM) in the sea-surface microlayer (SML) and the underlying water (ULW) were studied in a month-long mesocosm study, in May and June of 2023, at the Institute for Chemistry and Biology of the Marine Environment (ICBM) in Wilhelmshaven, Germany. The mesocosm study was conducted by the DFG research group BASS (Biogeochemical processes and Air–sea exchange in the Sea-Surface microlayer, Bibi et al., 2025) in the Sea Surface Facility (SURF) of the ICBM. The facility contains an 8 m × 1.5 m × 0.8 m large outdoor basin with a retractable roof, which was closed at night and during rain events. The basin was filled with North Sea water from the adjacent Jade Bay. Homogeneity of the ULW in the basin was achieved by constant mixing of the water column. The daily SML and ULW samples were collected alternating in the morning, about 1 h after sunrise, and in the afternoon, about 10 h after sunrise. The alternation of sampling times intended to capture a potential effect of sun-exposure duration on DOM transformations and elucidated the day and night variability of the layers. The SML was collected via glass plate sampling (Cunliffe and Wurl, 2014). The ULW was sampled via a submerged tube and a connected syringe suction system in 0.4 m depth. The removed sample volume was refilled with Jade Bay water every day. SML and ULW samples were filtered through pre-flushed 0.7 µm Whatman GF/F and 0.2 nucleopore filters into clear 40 ml SUPELCO bottles. These bottles were acid-washed twice and combusted at 500 °C for 5 h. The samples were stored dark and at 4 °C and measured within a few days of the study. FDOM was measured using a Aqualog fluorescence spectrometer (Horiba Scientific, Japan) with 10 seconds integration time and high gain of the CCD (charge-coupled device) sensor within an excitation range from 240 to 500 nm, and an emission range from 209.15 to 618.53 nm. The Aqualog measures fluorescence as well as absorption. The resulting data includes an excitation-emission-matrix (EEM) of the blank (MilliQ Starna cuvette), an EEM of the sample, and the absorption values of the sample. The raw exported Aqualog data was corrected for errors and lamp shifts. The corrected EEM data is then decomposed by PARAFAC (Murphy et al., 2013) for its underlying fluorophore components. Before running the PARAFAC routine, the corrected data needed to undergo a correction process by subtracting the blank from the sample EEM and canceling the influences of the inner-filter effect (IFE, Parker & Rees, 1962; Kothawala et al., 2013). The fluorescence intensity of the IFE-corrected EEM is calibrated by using the Raman scatter peak of water (Lawaetz & Stedmon, 2009). For PARAFAC the corrected data was processed using the drEEM and NWAY toolbox (version 0.6.5; Murphy et al., 2013) in MATLAB (R2020b). A 4-component model was validated with the validation style S4C6T3 for the split half analysis with nonnegativity constraints and 1-8e as the convergence criteria with 50 random starts and a maximum number of 2500 iterations. The resulting final model had a core consistency of 88.11 and the explained percentage was 99.55%. Furthermore, four fluorescence indices were calculated from the corrected EEM data (HIX – Humification index, Zsolnay et al., 1999; BIX – Biological index, Huguet et al., 2009; REPIX – Recently produced index, Parlanti et al., 2000, Drozdowska et al., 2015; ARIX, Murphy, 2025).
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