Changes in agroecosystem management (e.g. landscape diversity, management intensity) affect the natural control of pests. The effects of agricultural change on this ecosystem service, however, are not universal and the mechanisms affecting it remain to be understood. As biological control is effectively the product of networks of interactions between pests and their natural enemies, food web analysis provides a versatile tool to address this gap of knowledge. The proposed project will utilize a molecular food web approach and examine, for the first time, how changes in plant fertilisation and landscape complexity affect quantitative aphid-parasitoid-hyperparasitoid food webs on a species-specific level to unravel how changes in food web interactions affect parasitoid aphid control. Based on the fieldderived data, cage experiments will be conducted to assess how parasitoid diversity and identity affect parasitoid interactions and pest control, complementing the field results. The work proposed here will take research on parasitoid aphid control one step further, as it will provide a clearer understanding of how plant fertilization affects whole aphid-parasitoid food webs in both simple and complex landscapes, allowing for further improvements in natural pest control.
For surface soils, the mechanisms controlling soil organic C turnover have been thoroughly investigated. The database on subsoil C dynamics, however, is scarce, although greater than 50 percent of SOC stocks are stored in deeper soil horizons. The transfer of results obtained from surface soil studies to deeper soil horizons is limited, because soil organic matter (SOM) in deeper soil layers is exposed to contrasting environmental conditions (e.g. more constant temperature and moisture regime, higher CO2 and lower O2 concentrations, increasing N and P limitation to C mineralization with soil depth) and differs in composition compared to SOM of the surface layer, which in turn entails differences in its decomposition. For a quantitative analysis of subsoil SOC dynamics, it is necessary to trace the origins of the soil organic compounds and the pathways of their transformations. Since SOM is composed of various C pools which turn over on different time scales, from hours to millennia, bulk measurements do not reflect the response of specific pools to both transient and long-term change and may significantly underestimate CO2 fluxes. More detailed information can be gained from the fractionation of subsoil SOM into different functional pools in combination with the use of stable and radioactive isotopes. Additionally, soil-respired CO2 isotopic signatures can be used to understand the role of environmental factors on the rate of SOM decomposition and the magnitude and source of CO2 fluxes. The aims of this study are to (i) determine CO2 production and subsoil C mineralization in situ, (ii) investigate the vertical distribution and origin of CO2 in the soil profile using 14CO2 and 13CO2 analyses in the Grinderwald, and to (iii) determine the effect of environmental controls (temperature, oxygen) on subsoil C turnover. We hypothesize that in-situ CO2 production in subsoils is mainly controlled by root distribution and activity and that CO2 produced in deeper soil depth derives to a large part from the mineralization of fresh root derived C inputs. Further, we hypothesize that a large part of the subsoil C is potentially degradable, but is mineralized slower compared with the surface soil due to possible temperature or oxygen limitation.
Chlorinated ethylenes are prevalent groundwater contaminants. Numerous studies have addressed the mechanism of their reductive dehalogenation during biodegradation and reaction with zero-valent iron. However, despite insight with purified enzymes and well-characterized chemical model systems, conclusive evidence has been missing that the same mechanisms do indeed prevail in real-world transformations. While dual kinetic isotope effect measurements can provide such lines of evidence, until now this approach has not been possible for chlorinated ethylenes because an adequate method for continuous flow compound specific chlorine isotope analysis has been missing. This study attempts to close this prevalent research gap by a combination of two complementary approaches. (1) A novel analytical method to measure isotope effects for carbon and chlorine. (2) A carefully chosen set of well-defined model reactants representing distinct dehalogenation mechanisms believed to be important in real-world systems. Isotope trends observed in biotic and abiotic environmental dehalogenation will be compared to these model reactions, and the respective mechanistic hypotheses will be confirmed or discarded. With this hypothesis-driven approach it is our goal to elucidate for the first timdehalogenation reactions.
Der schnelle Fortschritt der elektronischen Geräte erhöht die Nachfrage nach verbesserten Li-Ionen Batterien. Kommerziell erhältliche Li-Zellen nutzen meist Lithiumkobaltoxid für die positive Elektrode. Doch gerade dieses Material ist ein Hindernis für eine weitere Optimierung, insbesondere für eine Kostensenkung. Vor allem für größere Anwendungen wie Hybrid- oder Elektrofahrzeuge müssen alternative Materialen erforscht werden, die billiger, sicherer und umweltverträglicher sind. Daher wird im ISEA derzeit ein neues Forschungsprojekt ins Leben gerufen und die dafür benötigte Infrastruktur geschaffen. Die Forschung wird sich auf die Untersuchung geeigneter Übergangsmetalloxide und Polyanionen konzentrieren, die besonders gut zur Einlagerung von Li-Ionen geeignet sind. Es werden neue Herstellungsverfahren unter Verwendung wässriger Precurser-Substanzen untersucht, die Verbindungen mit überlegenen Eigenschaften erzeugen und außerdem leicht an eine Massenproduktion angepasst werden können. Ziel der Arbeiten ist, preisgünstiges Elektrodenmaterial zu entwickeln, das eine spezifische Energie von über 200 Wh/kg und eine Leistungsdichte von 400 W/kg aufweist. Außerdem werden Arbeiten im Bereich der physikalisch-chemischen Charakterisierung der neuen Materialien stattfinden sowie elektrochemische Analysen der gesamten Zellen- und Batteriesysteme durchgeführt. Das elektrodynamische Verhalten der neuen Zellen wird u. a. mit Hilfe der elektrochemischen Impedanzspektroskopie analysiert, um präzise und zuverlässige Algorithmen für ein späteres Batteriemonitoring im realen Betrieb zu finden.
The broad objective of the research is to gain a fundamental understanding of the surface reaction chemistry of exhaust catalysts operating under cycling conditions. Using an integrated theoretical approach we specifically target NOx abatement, with particular emphasis on the appearance and destruction of surface oxide phases as the reactor conditions cycle from oxidative to reductive during the operation of the NOx Storage Reduction (NSR) catalyst system. Methodologically this requires material-specific, quantitative and explicitly time-dependent simulation tools that can follow the evolution of the system over the macroscopic time-scales of NSR cycles, while simultaneously accounting for the atomic-scale site heterogeneity and spatial distributions at the evolving surface. To meet these challenging demands we will develop a novel multi-scale methodology relying on a multi-lattice first-principles kinetic Monte Carlo (kMC) approach. As representative example the simulations will be carried out on a PdO(101)/Pd(100) surface oxide model, but care will be taken to ensure a generalization of the multi-lattice first-principles kMC approach to other systems in which phase transformations may occur and result in a change in the surface lattice structure depending upon environmental variables.
The final goal of the EUROWET project is to integrate the substantial multidisciplinary European research in wetlands to help attain the sustainable management of the water cycle. This will be achieved by the translation of state-of-the art science developed at both national and European levels, into practical guidance for end-users. This will be achieved by a comprehensive review, expert assessment and a focussed dissemination strategy. There is considerable scientific knowledge and technical experience gained in diverse aspects of wetland science and management including hydrology, biogeochemistry, ecology restoration, socio-economic and policy analysis. However the results of research and management experience are still too fragmentary and not sufficiently orientated to problem-solving or simply inadequately framed to be effectively transferred to, or used by, stakeholders and policy-makers. Simultaneously the general outcome of the scientific research has been increased awareness of the significance of wetlands in delivering goods and services important for human welfare including quality of life, biodiversity conservation and maintenance or enhancement of environment quality. Despite this wetlands continue to be degraded and lost throughout Europe without adequate consideration of the wider benefits to be achieved from this management. The new Water Framework Directive (WFD) promotes a unique opportunity to redress this problem by means of the holistic, integrated approach to water management. There is currently in preparation horizontal guidance on Wetlands as part of the Common Implementation Strategy (CIS) process. There is however work still to be done on providing more specific scientific and technical guidance on the effective implementation of the Directive with respect to wetlands. This is particularly the case in relation to Integrated River Management, the CIS cluster within which wetlands are being considered in the WFD.
Groundwater contamination by organic compounds represents a widespread environmental problem. The heterogeneity of geological formations and the complexity of physical and biogeochemical subsurface processes, often hamper a quantitative characterization of contaminated aquifers. Compound specific stable isotope analysis (CSIA) has emerged as a novel approach to investigate contaminant transformation and to relate contaminant sources to downgradient contamination. This method generally assumes that only (bio)chemical transformations are associated with isotope effects. However, recent studies have revealed isotope fractionation of organic contaminants by physical processes, therefore pointing to the need of further research to determine the influence of both transport and reactive processes on the observed overall isotope fractionation. While the effect of gasphase diffusion on isotope ratios has been studied in detail, possible effects of aqueous phase diffusion and dispersion have received little attention so far.The goals of this study are to quantify carbon (13C/12C) and, for chlorinated compounds, chlorine (37Cl/35Cl) isotope fractionation during diffusive/dispersive transport of organic contaminants in groundwater and to determine its consequences for source allocation and assessment of reactive processes using isotopes. The proposed research is based on the combination of high-resolution experimental studies, both at the laboratory (i.e. zero-, one- and two-dimensional systems) and at the field scales, and solute transport modeling. The project combines the expertise in the field of contaminant transport with the expertise on isotope methods in contaminant hydrogeology.
Comprehension of belowground competition between plant species is a central part in understanding the complex interactions in intercropped agricultural systems, between crops and weeds as well as in natural ecosystems. So far, no simple and rapid method for species discrimination of roots in the soil exists. We will be developing a method for root discrimination of various species based on Fourier Transform Infrared (FTIR)-Attenuated Total Reflexion (ATR) Spectroscopy and expanding its application to the field. The absorbance patterns of FTIR-ATR spectra represent the chemical sample composition like an individual fingerprint. By means of multivariate methods, spectra will be grouped according to spectral and chemical similarity in order to achieve species discrimination. We will investigate pea and oat roots as well as maize and barnyard grass roots using various cultivars/proveniences grown in the greenhouse. Pea and oat are recommendable species for intercropping to achieve superior grain and protein yields in an environmentally sustainable manner. To evaluate the effects of intercropping on root distribution in the field, root segments will be measured directly at the soil profile wall using a mobile FTIR spectrometer. By extracting the main root compounds (lipids, proteins, carbohydrates) and recording their FTIR-ATR spectra as references, we will elucidate the chemical basis of species-specific differences.
Fusarium species of the Gibberella fujikuroi species complex cause serious diseases on different crops such as rice, wheat and maize. An important group of plant pathogens is the Gibberella fujikuroi species complex (GFC) of closely related Fusarium species which are associated with specific hosts; F. verticillioides and F. proliferatum are particularly associated with maize where they can cause serious ear-, root-, and stalk rot diseases. Two other closely related species of the GFC, F. mangiferae and F. fujikuroi, which share about 90Prozent sequence identity with F. verticillioides, are pathogens on mango and rice, respectively. All of these species produce a broad spectrum of secondary metabolites such as phytohormones (gibberellins, auxins, and cytokinins), and harmful mycotoxins, such as fumonisin, fusarin C, or fusaric acid in large quantities. However, the spectrum of those mycotoxins might differ between closely related species suggesting that secondary metabolites might be determinants for host specificity. In this project, we will study the potential impact of secondary metabolites (i.e. phytohormones and certain mycotoxins) and some other species-specific factors (e.g. species-specific transcription factors) on host specificity. The recently sequenced genomes of F. mangiferae and F. fujikuroi by our groups and the planned sequencing of F. proliferatum will help to identify such determinants by genetic manipulation of the appropriate metabolic pathway(s).
The increasing proportion of carbon fibre reinforced plastics (CFRP) in different branches of industry will result in an increasingly larger quantity of CFRP wastes in future. With regard to improved management of natural resources, it is necessary to add these fibres that require energy-intensive production to effective recycling management. But high-quality material recycling is only ecoefficient if the recycled fibres can be used to produce new high-quality and marketable products. Tests carried out up to now indicate that very good results can be expected for large-scale recycling of carbon fibres by means of pyrolysis. The waste pyrolysis plant (WPP) operated in Burgau is the only large-scale pyrolysis plant for municipal wastes in Germany. Use of this plant to treat CFRP wastes represents a unique opportunity for the whole Southern German economy and in particular the Augsburg economic region. In a study funded by the Bavarian State Ministry of the Environment and Health ('Bayerisches Staatsministerium für Umwelt und Gesundheit'), the specific implementation options for the recovery of carbon fibres from composites by means of large-scale pyrolysis have been under investigation since November 2010. To this end, in the first step a development study was carried out, which in particular examined the options for modifying the Burgau WPP for the recycling of CFRP. The knowledge acquired from the pyrolysis tests, the fibre tests and the economic feasibility study confirmed the positive assessment of the overall concept of CFRP recycling in Burgau. As an overall result, unlimited profitability was found for all scenarios with regard to investments in CFRP recycling in Burgau WPP. The work on the development study was carried out by bifa Umweltinstitut GmbH together with the Augsburg-based 'function integrated lightweight construction project group ('Funktionsintegrierter Leichtbau' - FIL) of the Fraunhofer Institute for Chemical Technology (ICT). Methods: analysis and moderation of social processes, economy and management consulting, process engineering
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