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This data set is the source of my doctoral thesis and of three resulting publications. Through whole rock geochemistry of selected samples and microprobe and geochronological analyses of key minerals, formerly selected by extensive microscopical studies, standard geothermobarometry and modelling was applied. It has been shown that metamorphic rocks, in particular, the eclogites of the northern Kaghan Valley, Pakistan, were buried to depths of 140-100 km (36-30 kbar) at 790-640°C. Subsequently, cooling during decompression (exhumation) towards 40-35 km (17-10 kbar) and 630-580°C has been superseded by a phase of reheating to about 720-650°C at roughly the same depth before final exhumation has taken place. In the southern-most part of the Kaghan Valley, amphibolite facies assemblages with formation conditions similar to the deduced reheating phase indicate a juxtaposition of both areas after the eclogite facies stage and thus a stacking of Indian Plate units. Radiometric dating of zircon, titanite and rutile by U-Pb and amphibole and micas by Ar-Ar reveal peak pressure conditions at 47-48 Ma. With a maximum exhumation rate of 14 cm/a these rocks reached the crust-mantle boundary at 40-35 km within 1 Ma. Subsequent exhumation (46-41 Ma, 40-35 km) decelerated to ca. 1 mm/a at the base of the continental crust but rose again to about 2 mm/a in the period of 41-31 Ma, equivalent to 35-20 km. Apatite fission track (AFT) and (U-Th)/He ages from eclogites, amphibolites, micaschists and gneisses yielded moderate Oligocene to Miocene cooling rates of about 10°C/Ma in the high altitude northern parts of the Kaghan Valley using the mineral-pair method. AFT ages are of 24.5±3.8 to 15.6±2.1 Ma whereas apatite (U-Th)/He analyses yielded ages between 21.0±0.6 and 5.3±0.2 Ma. The southern-most part of the Valley is dominated by younger late Miocene to Pliocene apatite fission track ages of 7.6±2.1 and 4.0±0.5 Ma that support earlier tectonically and petrologically findings of a juxtaposition and stack of Indian Plate units. As this nappe is tectonically lowermost, a later distinct exhumation and uplift driven by thrusting along the Main Boundary Thrust is inferred. Out of this geochemical, petrological, isotope-geochemical and low temperature thermochronology investigations it was concluded that the exhumation was buoyancy driven and caused an initial rapid exhumation: exhumation as fast as recent normal plate movements (ca. 10 cm/a). As the exhuming units reached the crust-mantle boundary the process slowed down due to changes in buoyancy. Most likely, this exhumation pause has initiated the reheating event that is petrologically evident (e.g. glaucophane rimmed by hornblende, ilmenite overgrowth of rutile). Late stage processes involved widespread thrusting and folding with accompanied regional greenschist facies metamorphism, whereby contemporaneous thrusting on the Batal Thrust (seen sometimes equivalent to the MCT) and back sliding of the Kohistan Arc along the inverse reactivated Main Mantle Thrust caused final exposure of these rocks. Similar circumstances have been seen at Tso Morari, Ladakh, India, 200 km further east where comparable rock assemblages occur. In conclusion, as exhumation was already done well before the initiation of the monsoonal system, climate dependent effects (erosion) appear negligible in comparison to far-field tectonic effects. Thus, the channel flow model is not applicable for this part of the Himalayas.
This data set is the 1st part of a mini-series assembling whole-rock chemical data for late-Variscan granites of the Erzgebirge-Vogtland metallogenic province in the German Erzgebirge, in the Saxothuringian Zone of the Variscan Orogen, which is dedicated to the group of P-F-rich Li-mica granites. Listed are data from the massifs/plutons of Eibenstock in the western Erzgebirge and Annaberg, Geyer, Pobershau, and Seiffen in the central Erzgebirge (Figure 1). All these occurrences represent composite bodies made-up of texturally and geochemically distinct, but cogenetic sub-intrusions, which are associated with intra- und perigranitic aplitic dykes, pegmatitic schlieren, and frequently mineralized quartz veins and greisens (Tables 1-3). These granites exhibit moderately to strongly elevated concentrations of P, F, Li, Rb, Cs, Ta, Sn, W and U, but are low to very low in Ti, Mg, V, Sc, Co, Ni, Sr, Ba, Y, Zr, Hf, Th, and the REEs. Crystal-melt fractionation was the dominant process controlling the evolution of bulk composition in the course of massif/pluton formation. However, metasomatic processes involving late-stage residual melts and high-T late- to postmagmatic fluids became increasingly more important in highly evolved units and have variably modified the abundances of mobile elements (P, F, Li, Rb, Cs, Ba, Sr). Interaction with the various country rocks and infiltration of meteoric low-T fluids have further disturbed the initial chemical patterns. The data set reports whole-rock geochemical analyses for granites, aplites, and endocontact rocks obtained for the massifs/plutons of Eibenstock, Pobershau, Satzung, Annaberg, and Geyer. Data are provided as separate excel and csv files. The content of the excel sheet and further information on the granites and regional geology are provided in the data description file.
This data set is Part 2 of the compiles whole-rock chemical data for late-Variscan low-F biotite and two-mica granites in the German Erzgebirge, in the Saxothuringian Zone of the Variscan Orogen. The group of F-poor biotite granites is represented by the composite massifs of Kirchberg and Niederbobritzsch, the Plohn Granite Suite (PGS), the Aue Granite Suite (AGS), and the subsurface granites of Beiersdorf und Bernsbach. For the group of two-mica granites, compositional data for the multi-stage Bergen massif and the granites from Lauter and Schwarzenberg are reported (Figure 1). Crystal-melt fractionation was the dominant process controlling the evolution of bulk composition in the course of massif/pluton formation. However, metasomatic and hydrothermal processes involving late-stage residual melts and high-T late- to post-magmatic fluids became increasingly more important in highly evolved units and have variably modified the abundances of mobile elements. Interaction with the various metamorphic country rocks and infiltration of meteoric low-T fluids have further disturbed the initial chemical patterns in the endocontact zones and zones influenced by surface weathering. The data set reports whole-rock geochemical analyses for enclaves, granites, aplites, endocontact rocks, and some facial varieties. The data are presented as Excel (xlsx) and machine-readable txt formats. The content of the excel sheet and further information on the granites and regional geology are provided in the data description file.
These data represent the most complete set of analyses of the Eastern Australian Potassic suite. The data include whole-rock major-, trace-, and volatile-element analyses including loss-on-ignition measurements for 48 samples from 21 spatially distinct leucite-bearing volcanic surface expressions. These expressions range from topographically prominent volcanic edifices and mounds, through to lava flows, with four sample locations (8 samples total) coming from active quarry sites. Location and elevation data as well as methods used are provided. Trace-element data are available for 45 samples and include a total of 41 elements, while volatile-element data are available for 47 samples. All samples have major element analyses (10 elements). This is an update on the dataset provided in version 1 (https://doi.org/10.25625/AB5PLG). Additional information on the sample texture, description, and analytical methods has been added. This update also rectifies mismatches between some trace-element analyses and the corresponding samples. Data for Sn have been removed due to poor accuracy and precision.
The data presented are whole-rock geochemical analyses (major and minor elements, REE) of highliy deformed and metamorphosed rocks of the Middle and Eastern Erzgebirge nappe stacks. Geochemical discrimination was used to identify the protolith nature of a sample series representing metasedimentary, metagranitoidic, metarhyolitic, and metabasaltic rock types. Discrimination between para- and orthogneisses was also supported by mathematical factor analysis. According to new geochronological data, ages of the sample series range between Neoproterozoic to Ordovician. Analyses with different methods (ICP, AAS, XRF, OES, WET) were made between 1979 and 1991 in different laboratories of the German Democratic Republic (GDR) and the early GFZ German Research Centre for Geosciences. Economical constraints limited the capacity of and access to labs, and also available techniques in the GDR - limiting the spectrum of elements to be analysed, especially that of REE, as well. Switching from lab to lab (see table) became a neccessary tool. Despite these problems, all data proved to be comparable. This also applies in comparison to data from later used techniques (ICP, from 1991 on) on some additional sample material, regardless of its higher resolution. In few cases, detection limits have not been communicated (see template). The data are reported with the EarthChem Templates (https://doi.org/10.26022/IEDA/112263). German title: Gesamtgesteins-Geochemie (Haupt-, Spurenelemente, REE) an hoch-deformierten und metamorphosierten Gesteinen der Mittel- und Osterzgebirgirgischen Deckenstapel
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