Sediment erosion and transport is critical to the ecological and commercial health of aquatic habitats from watershed to sea. There is now a consensus that microorganisms inhabiting the system mediate the erosive response of natural sediments ('ecosystem engineers') along with physicochemical properties. The biological mechanism is through secretion of a microbial organic glue (EPS: extracellular polymeric substances) that enhances binding forces between sediment grains to impact sediment stability and post-entrainment flocculation. The proposed work will elucidate the functional capability of heterotrophic bacteria, cyanobacteria and eukaryotic microalgae for mediating freshwater sediments to influence sediment erosion and transport. The potential and relevance of natural biofilms to provide this important 'ecosystem service' will be investigated for different niches in a freshwater habitat. Thereby, variations of the EPS 'quality' and 'quantity' to influence cohesion within sediments and flocs will be related to shifts in biofilm composition, sediment characteristics (e.g. organic background) and varying abiotic conditions (e.g. light, hydrodynamic regime) in the water body. Thus, the proposed interdisciplinary work will contribute to a conceptual understanding of microbial sediment engineering that represents an important ecosystem function in freshwater habitats. The research has wide implications for the water framework directive and sediment management strategies.
Der Kartendienst (WMS Gruppe) stellt Geodaten aus dem Bereich Mobilität im Saarland dar.:Raster 1000m symbolisiert nach dem Attribut "Anteil attraktiver Wege ÖV" im Zeitraum zwischen 3 und 6 Uhr.
It is well established that reduced supply of fresh organic matter, interactions of organic matter with mineral phases and spatial inaccessibility affect C stocks in subsoils. However, quantitative information required for a better understanding of the contribution of each of the different processes to C sequestration in subsoils and for improvements of subsoil C models is scarce. The same is true for the main controlling factors of the decomposition rates of soil organic matter in subsoils. Moreover, information on spatial variabilities of different properties in the subsoil is rare. The few studies available which couple near and middle infrared spectroscopy (NIRS/MIRS) with geostatistical approaches indicate a potential for the creation of spatial maps which may show hot spots with increased biological activities in the soil profile and their effects on the distribution of C contents. Objectives are (i) to determine the mean residence time of subsoil C in different fractions by applying fractionation procedures in combination with 14C measurements; (ii) to study the effects of water content, input of 13C-labelled roots and dissolved organic matter and spatial inaccessibility on C turnover in an automatic microcosm system; (iii) to determine general soil properties and soil biological and chemical characteristics using NIRS and MIRS, and (iv) to extrapolate the measured and estimated soil properties to the vertical profiles by using different spatial interpolation techniques. For the NIRS/MIRS applications, sample pretreatment (air-dried vs. freeze-dried samples) and calibration procedures (a modified partial least square (MPLS) approach vs. a genetic algorithm coupled with MPLS or PLS) will be optimized. We hypothesize that the combined application of chemical fractionation in combination with 14C measurements and the results of the incubation experiments will give the pool sizes of passive, intermediate, labile and very labile C and N and the mean residence times of labile and very labile C and N. These results will make it possible to initialize the new quantitative model to be developed by subproject PC. Additionally, we hypothesize that the sample pretreatment 'freeze-drying' will be more useful for the estimation of soil biological characteristics than air-drying. The GA-MPLS and GA-PLS approaches are expected to give better estimates of the soil characteristics than the MPLS and PLS approaches. The spatial maps for the different subsoil characteristics in combination with the spatial maps of temperature and water contents will presumably enable us to explain the spatial heterogeneity of C contents.
Perennial fodder cropping potentially increases subsoil biopore density by formation of extensive root systems and temporary soil rest. We will quantify root length density, earthworm abundance and biopore size classes after Medicago sativa, Cichorium intybus and Festuca arundinacea grown for 1, 2 and 3 years respectively in the applied research unit's Central Field Trial (CeFiT) which is established and maintained by our working group. Shoot parameters including transpiration, gas exchange and chlorophyll fluorescence will frequently be recorded. Precrop effects on oilseed rape and cereals will be quantified with regard to crop yield, nutrient transfer and H2-release. The soil associated with biopores (i.e. the driloshpere) is generally rich in nutrients as compared to the bulk soil and is therefore supposed to be a potential hot spot for nutrient acquisition. However, contact areas between roots and the pore wall have been reported to be low. It is still unclear to which extent the nutrients present in the drilosphere are used and which potential relevance subsoil biopores may have for the nutrient supply of crops. We will use a flexible videoscope to determine the root-soil contact in biopores. Nitrogen input into the drilosphere by earthworms and potential re-uptake of nitrogen from the drilosphere by subsequent crops with different rooting systems (oilseed rape vs. cereals) will be quantified using 15N as a tracer.
Ziel des Projektes ist eine Bestandsaufnahme der Wassermassenverteilung und der Zirkulation im Arktischen Ozean. Stabile Sauerstoffisotopen (delta18O) des Wassers ist ein konservativer Tracer und werden zusammen mit hydrochemischen Daten dazu verwendet das vom Schelf stammende Süßwasser (Flusswasser und Meereis-Schmelze oder Bildung) und die aus dem Pazifik stammende Komponente zu untersuchen. Auf diese Weise wird der Einfluss dieser Wassermassen in der arktischen Salzgehaltsschichtung (Halokline), dem Atlantischen Zwischenwasser und dem Tiefen- und Bodenwasser des Arktischen Ozeans quantifiziert werden. Es ist bekannt, dass die Verteilung der Pazifischen Komponente starken Veränderungen auf dekadischen Zeitskalen unterliegt aber auch in den Süßwasserverteilungen im Transpolaren Drift Strom wurden 2007 starke Variationen beobachtet welche somit auf zusätzliche jährliche Variationen hinweisen. Es ist nicht bekannt ob die 2007 beobachteten Variationen ein permanentes Phänomen sind und ob diese mit dem weitgehenden Fehlen des Pazifischen Wassers in diesem Zeitraum zusammenhängen. Die geplante flächendeckende und quantitative Erfassung der Süßwasserverteilung und des Pazifischen Wassers werden daher dazu beitragen, den Einfluss und die möglichen Rückkopplungsmechanismen der arktischen Hydrographie auf den arktischen und globalen Klimawandel weitergehend zu verstehen.
Arsenic-contaminated ground- and drinking water is a global environmental problem with about 1-2Prozent of the world's population being affected. The upper drinking water limit for arsenic (10 Micro g/l) recommended by the WHO is often exceeded, even in industrial nations in Europe and the USA. Chronic intake of arsenic causes severe health problems like skin diseases (e.g. blackfoot disease) and cancer. In addition to drinking water, seafood and rice are the main reservoirs for arsenic uptake. Arsenic is oftentimes of geogenic origin and in the environment it is mainly bound to iron(III) minerals. Iron(III)-reducing bacteria are able to dissolve these iron minerals and therefore release the arsenic to the environment. In turn, iron(II)-oxidizing bacteria have the potential to co-precipitate or sorb arsenic during iron(II)- oxidation at neutral pH followed by iron(III) mineral precipitation. This process may reduce arsenic concentrations in the environment drastically, lowering the potential risk for humans dramatically.The main goal of this study therefore is to quantify, identify and isolate anaerobic and aerobic Fe(II)-oxidizing microorganisms in arsenic-containing paddy soil. The co-precipitation and thus removal of arsenic by iron mineral producing bacteria will be determined in batch and microcosm experiments. Finally the influence of rhizosphere redox status on microbial Fe oxidation and arsenic uptake into rice plants will be evaluated in microcosm experiments. The long-term goal of this research is to better understand arsenic-co-precipitation and thus arsenic-immobilization by iron(II)-oxidizing bacteria in rice paddy soil. Potentially these results can lead to an improvement of living conditions in affected countries, e.g. in China or Bangladesh.
Chromium (Cr) is introduced into the environment by several anthropogenic activities. A striking ex-ample is the area around Kanpur in the Indian state of Uttar Pradesh, where large amounts of Cr-containing wastes have been recently illegally deposited. Hexavalent Cr, a highly toxic and mobile contaminant, is present in significant amounts in these wastes, severely affecting the quality of sur-roundings soils, sediments, and ground waters. The first major goal of this study is to clarify the solid phase speciation of Cr in these wastes and to examine its leaching behavior. X-ray diffraction and synchrotron-based X-ray absorption spectroscopy techniques will be employed for quantitative solid phase speciation of Cr. Its leaching behavior will be studied in column experiments performed at un-saturated moisture conditions with flow interruptions simulating monsoon rain events. Combined with geochemical modeling, the results will allow the evaluation of the leaching potential and release kinetics of Cr from the waste materials. The second major goal is to investigate the spatial distribution, speciation, and solubility of Cr in the rooting zone of chromate-contaminated soils surrounding the landfills, and to study the suitability of biochar as novel soil amendment for mitigating the deleterious effects of chromate pollution. Detailed field samplings and laboratory soil incubation studies will be carried out with two agricultural soils and biochar from the Kanpur region.
The decomposition of terrestrial organic material such as leaf litter represents a fundamental ecosystem function in streams that delivers energy for local and downstream food webs. Although agriculture dominates most regions in Europe and fungicides are applied widely, effects of currently used fungicides on the aquatic decomposer community and consequently the leaf decomposition rate are largely unknown. Also potential compensation of such hypothesised adverse effects due to nutrients or higher average water temperatures associated with climate change are not considered. Moreover, climate change is predicted to alter the community of aquatic decomposers and an open question is, whether this alteration impacts the leaf decomposition rate. The current projects follows a tripartite design to answer these research questions. Firstly, a field study in a vine growing region where fungicides are applied in large amounts will be conducted to whether there is a dose-response relationship between the exposure to fungicides and the leaf decomposition rate. Secondly, experiments in artificial streams with field communities will be carried out to assess potential compensatory mechanisms of nutrients and temperature for effects of fungicides. Thirdly, field experiments with communities exhibiting a gradient of taxa sensitive to climate change will be used to investigate potential climate-related effects on the leaf decomposition rate.
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